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For other uses, see Asphalt (disambiguation). Note: The terms bitumen and asphalt are mostly interchangeable, Pavement Sealer in South Africa except where asphalt is used as a shorthand for asphalt concrete. Natural bitumen from the Dead Sea Refined asphalt The University of Queensland pitch drop experiment, demonstrating the viscosity of asphalt

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Asphalt (/ˈæsˌfɔːlt, -ˌfɑːlt/), also known as bitumen (UK English: /ˈbɪtʃəmən, ˈbɪtjʊmən/,[1] US English: /bɪˈt(j)uːmən, baɪˈt(j)uːmən/)[2] is a sticky, black, and highly viscous liquid or semi-solid form of petroleum. It may be found in natural deposits or may be a refined product, and is classed as a pitch. Before the 20th century, the term asphaltum was also used.

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The primary use (70%) of asphalt Asphalt Sealcoating Companies is in road construction, where it is used as the glue or binder mixed with aggregate particles to create asphalt concrete. Its other main uses are for bituminous waterproofing products, including production of roofing felt and for sealing flat roofs.

The terms “asphalt” and “bitumen” are often used interchangeably to mean both natural and manufactured forms of the substance. In American English, “asphalt” (or “asphalt cement”) is commonly used for a refined residue from the distillation process of selected crude oils. Outside the United States, the product is often called “bitumen”, and geologists worldwide often prefer the term for the naturally occurring variety. Common colloquial usage often refers to various forms of asphalt as “tar”, as in the name of the La Brea Tar Pits.

Asphalt

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Naturally occurring asphalt is sometimes specified by the term “crude bitumen”. Pavement Sealer Its viscosity is similar to that of cold molasses[6][7] while the material obtained from the fractional distillation of crude oil boiling at 525 °C (977 °F) is sometimes referred to as “refined bitumen”. The Canadian province of Alberta has most of the world’s reserves of natural asphalt in the Athabasca oil sands, which cover 142,000 square kilometres (55,000 sq mi), an area larger than England.

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The word “asphalt” is derived from the late Middle English, in turn from French asphalte, based on Late Latin asphalton, asphaltum, which is the latinisation of the Greek ἄσφαλτος (ásphaltos, ásphalton), a word meaning “asphalt/bitumen/pitch” which perhaps derives from ἀ-, “without” and σφάλλω (sfallō), “make fall”.  Asphalt Driveway Coating the first use of asphalt by the ancients was in the nature of a cement for securing or joining together various objects, and it thus seems likely that the name itself was expressive of this application. Specifically, Herodotus mentioned that bitumen was brought to Babylon to build its gigantic fortification wall.[11] From the Greek, the word passed into late Latin, and thence into French (asphalte) and English (“asphaltum” and “asphalt”). In French, the term asphalte is used for naturally occurring asphalt-soaked limestone deposits, and for specialised manufactured products with fewer voids or greater bitumen content than the “asphaltic concrete” used to pave roads.

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The expression “bitumen” originated in the Sanskrit words jatu, meaning “pitch”, and jatu-krit, meaning “pitch creating” or “pitch producing” (referring to coniferous or resinous trees). The Latin equivalent is claimed by some to be originally gwitu-men (pertaining to pitch), and by others, pixtumens (exuding or bubbling pitch), which was subsequently shortened to bitumen, thence passing via French into English. From the same root is derived the Anglo-Saxon word cwidu (mastix), the German word Kitt (cement or mastic) and the old Norse word kvada.

In British English, “bitumen” is used instead of “asphalt”. The word “asphalt” is instead used to refer to asphalt concrete, a mixture of construction aggregate and asphalt itself (also called “tarmac” in common parlance). Bitumen mixed with clay was usually called “asphaltum”,[13] but the term is less commonly used today.[citation needed]

Asphalt concrete

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In Australian English, “bitumen” is often used as the generic term for road surfaces.

In American English, “asphalt” is equivalent to the British “bitumen”. However, “asphalt” is also commonly used as a shortened form of “asphalt concrete” (therefore equivalent to the British “asphalt” or “tarmac”).

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In Canadian English, the word “bitumen” is used to refer to the vast Canadian deposits of extremely heavy crude oil,[14] while “asphalt” is used for the oil refinery product. Diluted bitumen (diluted with naphtha to make it flow in pipelines) is known as “dilbit” in the Canadian petroleum industry, while bitumen “upgraded” to synthetic crude oil is known as “syncrude”, and syncrude blended with bitumen is called “synbit”.[15]

“Bitumen” is still the preferred geological term for naturally occurring deposits of the solid or semi-solid form of petroleum. “Bituminous rock” is a form of sandstone impregnated with bitumen. The tar sands of Alberta, Canada are a similar material.

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Neither of the terms “asphalt” or “bitumen” should be confused with tar or coal tars.[further explanation needed]

See also: Asphaltene

The components of asphalt include four main classes of compounds:

The naphthene aromatics and polar aromatics are typically the majority components. Most natural bitumens also contain organosulfur compounds, resulting in an overall sulfur content of up to 4%. Nickel and vanadium are found at <10 parts per million, as is typical of some petroleum.

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The substance is soluble in carbon disulfide. It is commonly modelled as a colloid, with asphaltenes as the dispersed phase and maltenes as the continuous phase.[16] “It is almost impossible to separate and identify all the different molecules of asphalt, because the number of molecules with different chemical structure is extremely large”.

Asphalt may be confused with coal tar, which is a visually similar black, thermoplastic material produced by the destructive distillation of coal. During the early and mid-20th century, when town gas was produced, coal tar was a readily available byproduct and extensively used as the binder for road aggregates. The addition of coal tar to macadam roads led to the word “tarmac”, which is now used in common parlance to refer to road-making materials. However, since the 1970s, when natural gas succeeded town gas, asphalt has completely overtaken the use of coal tar in these applications. Other examples of this confusion include the La Brea Tar Pits and the Canadian oil sands, both of which actually contain natural bitumen rather than tar. “Pitch” is another term sometimes informally used at times to refer to asphalt, as in Pitch Lake.

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Bituminous outcrop of the Puy de la Poix, Clermont-Ferrand, France

The majority of asphalt used commercially is obtained from petroleum.[18] Nonetheless, large amounts of asphalt occur in concentrated form in nature. Naturally occurring deposits of bitumen are formed from the remains of ancient, microscopic algae (diatoms) and other once-living things. These remains were deposited in the mud on the bottom of the ocean or lake where the organisms lived. Under the heat (above 50 °C) and pressure of burial deep in the earth, the remains were transformed into materials such as bitumen, kerogen, or petroleum.

Natural deposits of bitumen include lakes such as the Pitch Lake in Trinidad and Tobago and Lake Bermudez in Venezuela. Natural seeps occur in the La Brea Tar Pits and in the Dead Sea.

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Bitumen also occurs in unconsolidated sandstones known as “oil sands” in Alberta, Canada, and the similar “tar sands” in Utah, US. The Canadian province of Alberta has most of the world’s reserves, in three huge deposits covering 142,000 square kilometres (55,000 sq mi), an area larger than England or New York state. These bituminous sands contain 166 billion barrels (26.4×10^9 m3) of commercially established oil reserves, giving Canada the third largest oil reserves in the world. Although historically it was used without refining to pave roads, nearly all of the output is now used as raw material for oil refineries in Canada and the United States.

Lane

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The world’s largest deposit of natural bitumen, known as the Athabasca oil sands, is located in the McMurray Formation of Northern Alberta. This formation is from the early Cretaceous, and is composed of numerous lenses of oil-bearing sand with up to 20% oil.[19] Isotopic studies show the oil deposits to be about 110 million years old.[20] Two smaller but still very large formations occur in the Peace River oil sands and the Cold Lake oil sands, to the west and southeast of the Athabasca oil sands, respectively. Of the Alberta deposits, only parts of the Athabasca oil sands are shallow enough to be suitable for surface mining. The other 80% has to be produced by oil wells using enhanced oil recovery techniques like steam-assisted gravity drainage.

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Much smaller heavy oil or bitumen deposits also occur in the Uinta Basin in Utah, US. The Tar Sand Triangle deposit, for example, is roughly 6% bitumen.

Bitumen may occur in hydrothermal veins. An example of this is within the Uinta Basin of Utah, in the US, where there is a swarm of laterally and vertically extensive veins composed of a solid hydrocarbon termed Gilsonite. These veins formed by the polymerization and solidification of hydrocarbons that were mobilized from the deeper oil shales of the Green River Formation during burial and diagenesis.

Asphalt Driveway Costs

Bitumen is similar to the organic matter in carbonaceous meteorites.[23] However, detailed studies have shown these materials to be distinct.[24] The vast Alberta bitumen resources are considered to have started out as living material from marine plants and animals, mainly algae, that died millions of years ago when an ancient ocean covered Alberta. They were covered by mud, buried deeply over time, and gently cooked into oil by geothermal heat at a temperature of 50 to 150 °C (120 to 300 °F). Due to pressure from the rising of the Rocky Mountains in southwestern Alberta, 80 to 55 million years ago, the oil was driven northeast hundreds of kilometres and trapped into underground sand deposits left behind by ancient river beds and ocean beaches, thus forming the oil sands.

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The use of natural bitumen for waterproofing, and as an adhesive dates at least to the fifth millennium BC, with a crop storage basket discovered in Mehrgarh, of the Indus Valley Civilization, lined with it.[25] By the 3rd millennia BC refined rock asphalt was in use, in the region, and was used to waterproof the Great Bath, Mohenjo-daro.

In the ancient Middle East, the Sumerians used natural bitumen deposits for mortar between bricks and stones, to cement parts of carvings, such as eyes, into place, for ship caulking, and for waterproofing.[3] The Greek historian Herodotus said hot bitumen was used as mortar in the walls of Babylon.

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The 1 kilometre (0.62 mi) long Euphrates Tunnel beneath the river Euphrates at Babylon in the time of Queen Semiramis (ca. 800 BC) was reportedly constructed of burnt bricks covered with bitumen as a waterproofing agent.

Bitumen was used by ancient Egyptians to embalm mummies.[3][28] The Persian word for asphalt is moom, which is related to the English word mummy. The Egyptians’ primary source of bitumen was the Dead Sea, which the Romans knew as Palus Asphaltites (Asphalt Lake).

Asphalt Driveway Price

Approximately 40 AD, Dioscorides described the Dead Sea material as Judaicum bitumen, and noted other places in the region where it could be found.[29] The Sidon bitumen is thought to refer to material found at Hasbeya.[30] Pliny refers also to bitumen being found in Epirus. It was a valuable strategic resource, the object of the first known battle for a hydrocarbon deposit—between the Seleucids and the Nabateans in 312 BC.

Asphalt Repair Quotes

In the ancient Far East, natural bitumen was slowly boiled to get rid of the higher fractions, leaving a thermoplastic material of higher molecular weight that when layered on objects became quite hard upon cooling. This was used to cover objects that needed waterproofing,[3] such as scabbards and other items. Statuettes of household deities were also cast with this type of material in Japan, and probably also in China.

In North America, archaeological recovery has indicated bitumen was sometimes used to adhere stone projectile points to wooden shafts.[32] In Canada, aboriginal people used bitumen seeping out of the banks of the Athabasca and other rivers to waterproof birch bark canoes, and also heated it in smudge pots to ward off mosquitoes in the summer.

Commercial Paving Cost Estimate

In 1553, Pierre Belon described in his work Observations that pissasphalto, a mixture of pitch and bitumen, was used in the Republic of Ragusa (now Dubrovnik, Croatia) for tarring of ships.

Brick

Asphalt Driveway Repair Price

An 1838 edition of Mechanics Magazine cites an early use of asphalt in France. A pamphlet dated 1621, by “a certain Monsieur d’Eyrinys, states that he had discovered the existence (of asphaltum) in large quantities in the vicinity of Neufchatel”, and that he proposed to use it in a variety of ways – “principally in the construction of air-proof granaries, and in protecting, by means of the arches, the water-courses in the city of Paris from the intrusion of dirt and filth”, which at that time made the water unusable. “He expatiates also on the excellence of this material for forming level and durable terraces” in palaces, “the notion of forming such terraces in the streets not one likely to cross the brain of a Parisian of that generation”.

Driveway Paving Cost Estimate

But the substance was generally neglected in France until the revolution of 1830. In the 1830s there was a surge of interest, and asphalt became widely used “for pavements, flat roofs, and the lining of cisterns, and in England, some use of it had been made of it for similar purposes”. Its rise in Europe was “a sudden phenomenon”, after natural deposits were found “in France at Osbann (Bas-Rhin), the Parc (Ain) and the Puy-de-la-Poix (Puy-de-Dôme)”, although it could also be made artificially.[35] One of the earliest uses in France was the laying of about 24,000 square yards of Seyssel asphalt at the Place de la Concorde in 1835.

Among the earlier uses of bitumen in the United Kingdom was for etching. William Salmon’s Polygraphice (1673) provides a recipe for varnish used in etching, consisting of three ounces of virgin wax, two ounces of mastic, and one ounce of asphaltum.[37] By the fifth edition in 1685, he had included more asphaltum recipes from other sources.

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The first British patent for the use of asphalt was “Cassell’s patent asphalte or bitumen” in 1834.[35] Then on 25 November 1837, Richard Tappin Claridge patented the use of Seyssel asphalt (patent #7849), for use in asphalte pavement,[39][40] having seen it employed in France and Belgium when visiting with Frederick Walter Simms, who worked with him on the introduction of asphalt to Britain.[41][42] Dr T. Lamb Phipson writes that his father, Samuel Ryland Phipson, a friend of Claridge, was also “instrumental in introducing the asphalte pavement (in 1836)”.[43] Indeed, mastic pavements had been previously employed at Vauxhall by a competitor of Claridge, but without success.

Boulevard

Asphalt Driveway Repair Price

Claridge obtained a patent in Scotland on 27 March 1838, and obtained a patent in Ireland on 23 April 1838. In 1851, extensions for the 1837 patent and for both 1838 patents were sought by the trustees of a company previously formed by Claridge. Claridge’s Patent Asphalte Company—formed in 1838 for the purpose of introducing to Britain “Asphalte in its natural state from the mine at Pyrimont Seysell in France”,—”laid one of the first asphalt pavements in Whitehall”.  Trials were made of the pavement in 1838 on the footway in Whitehall, the stable at Knightsbridge Barracks,”and subsequently on the space at the bottom of the steps leading from Waterloo Place to St. James Park”. “The formation in 1838 of Claridge’s Patent Asphalte Company (with a distinguished list of aristocratic patrons, and Marc and Isambard Brunel as, respectively, a trustee and consulting engineer), gave an enormous impetus to the development of a British asphalt industry”.[45] “By the end of 1838, at least two other companies, Robinson’s and the Bastenne company, were in production”,[50] with asphalt being laid as paving at Brighton, Herne Bay, Canterbury, Kensington, the Strand, and a large floor area in Bunhill-row, while meantime Claridge’s Whitehall paving “continue(d) in good order”.

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Paver Repair Quotes For other uses, see Asphalt (disambiguation). Note: The terms bitumen and asphalt are mostly interchangeable, except where asphalt is used as a shorthand for asphalt concrete. Natural bitumen from the Dead Sea Refined asphalt The University of Queensland pitch drop experiment, demonstrating the viscosity of asphalt

Asphalt (/ˈæsˌfɔːlt, -ˌfɑːlt/), also known as bitumen (UK English: /ˈbɪəmən, ˈbɪtjʊmən/,[1] US English: /bɪˈt(j)mən, bˈt(j)mən/)[2] is a sticky, black, and highly viscous liquid or semi-solid form of petroleum. It may be found in natural deposits or may be a refined product, and is classed as a pitch. Before the 20th century, the term asphaltum was also used.[3] The word is derived from the Ancient Greek ἄσφαλτος ásphaltos.[4]

The primary use (70%) of asphalt is in road construction, where it is used as the glue or binder mixed with aggregate particles to create asphalt concrete. Its other main uses are for bituminous waterproofing products, including production of roofing felt and for sealing flat roofs.[5]

The terms "asphalt" and "bitumen" are often used interchangeably to mean both natural and manufactured forms of the substance. In American English, "asphalt" (or "asphalt cement") is commonly used for a refined residue from the distillation process of selected crude oils. Outside the United States, the product is often called "bitumen", and geologists worldwide often prefer the term for the naturally occurring variety. Common colloquial usage often refers to various forms of asphalt as "tar", as in the name of the La Brea Tar Pits.

Naturally occurring asphalt is sometimes specified by the term "crude bitumen". Its viscosity is similar to that of cold molasses[6][7] while the material obtained from the fractional distillation of crude oil boiling at 525 °C (977 °F) is sometimes referred to as "refined bitumen". The Canadian province of Alberta has most of the world's reserves of natural asphalt in the Athabasca oil sands, which cover 142,000 square kilometres (55,000 sq mi), an area larger than England.[8]

The word "asphalt" is derived from the late Middle English, in turn from French asphalte, based on Late Latin asphalton, asphaltum, which is the latinisation of the Greek ἄσφαλτος (ásphaltos, ásphalton), a word meaning "asphalt/bitumen/pitch",[9] which perhaps derives from ἀ-, "without" and σφάλλω (sfallō), "make fall".[10] The first use of asphalt by the ancients was in the nature of a cement for securing or joining together various objects, and it thus seems likely that the name itself was expressive of this application. Specifically, Herodotus mentioned that bitumen was brought to Babylon to build its gigantic fortification wall.[11] From the Greek, the word passed into late Latin, and thence into French (asphalte) and English ("asphaltum" and "asphalt"). In French, the term asphalte is used for naturally occurring asphalt-soaked limestone deposits, and for specialised manufactured products with fewer voids or greater bitumen content than the "asphaltic concrete" used to pave roads.

The expression "bitumen" originated in the Sanskrit words jatu, meaning "pitch", and jatu-krit, meaning "pitch creating" or "pitch producing" (referring to coniferous or resinous trees). The Latin equivalent is claimed by some to be originally gwitu-men (pertaining to pitch), and by others, pixtumens (exuding or bubbling pitch), which was subsequently shortened to bitumen, thence passing via French into English. From the same root is derived the Anglo-Saxon word cwidu (mastix), the German word Kitt (cement or mastic) and the old Norse word kvada.[12]

In British English, "bitumen" is used instead of "asphalt". The word "asphalt" is instead used to refer to asphalt concrete, a mixture of construction aggregate and asphalt itself (also called "tarmac" in common parlance). Bitumen mixed with clay was usually called "asphaltum",[13] but the term is less commonly used today.[citation needed]

In Australian English, "bitumen" is often used as the generic term for road surfaces.

In American English, "asphalt" is equivalent to the British "bitumen". However, "asphalt" is also commonly used as a shortened form of "asphalt concrete" (therefore equivalent to the British "asphalt" or "tarmac").

In Canadian English, the word "bitumen" is used to refer to the vast Canadian deposits of extremely heavy crude oil,[14] while "asphalt" is used for the oil refinery product. Diluted bitumen (diluted with naphtha to make it flow in pipelines) is known as "dilbit" in the Canadian petroleum industry, while bitumen "upgraded" to synthetic crude oil is known as "syncrude", and syncrude blended with bitumen is called "synbit".[15]

"Bitumen" is still the preferred geological term for naturally occurring deposits of the solid or semi-solid form of petroleum. "Bituminous rock" is a form of sandstone impregnated with bitumen. The tar sands of Alberta, Canada are a similar material.

Neither of the terms "asphalt" or "bitumen" should be confused with tar or coal tars.[further explanation needed]

See also: Asphaltene

The components of asphalt include four main classes of compounds:

The naphthene aromatics and polar aromatics are typically the majority components. Most natural bitumens also contain organosulfur compounds, resulting in an overall sulfur content of up to 4%. Nickel and vanadium are found at <10 parts per million, as is typical of some petroleum.[5]

The substance is soluble in carbon disulfide. It is commonly modelled as a colloid, with asphaltenes as the dispersed phase and maltenes as the continuous phase.[16] "It is almost impossible to separate and identify all the different molecules of asphalt, because the number of molecules with different chemical structure is extremely large".[17]

Asphalt may be confused with coal tar, which is a visually similar black, thermoplastic material produced by the destructive distillation of coal. During the early and mid-20th century, when town gas was produced, coal tar was a readily available byproduct and extensively used as the binder for road aggregates. The addition of coal tar to macadam roads led to the word "tarmac", which is now used in common parlance to refer to road-making materials. However, since the 1970s, when natural gas succeeded town gas, asphalt has completely overtaken the use of coal tar in these applications. Other examples of this confusion include the La Brea Tar Pits and the Canadian oil sands, both of which actually contain natural bitumen rather than tar. "Pitch" is another term sometimes informally used at times to refer to asphalt, as in Pitch Lake.

Bituminous outcrop of the Puy de la Poix, Clermont-Ferrand, France

The majority of asphalt used commercially is obtained from petroleum.[18] Nonetheless, large amounts of asphalt occur in concentrated form in nature. Naturally occurring deposits of bitumen are formed from the remains of ancient, microscopic algae (diatoms) and other once-living things. These remains were deposited in the mud on the bottom of the ocean or lake where the organisms lived. Under the heat (above 50 °C) and pressure of burial deep in the earth, the remains were transformed into materials such as bitumen, kerogen, or petroleum.

Natural deposits of bitumen include lakes such as the Pitch Lake in Trinidad and Tobago and Lake Bermudez in Venezuela. Natural seeps occur in the La Brea Tar Pits and in the Dead Sea.

Bitumen also occurs in unconsolidated sandstones known as "oil sands" in Alberta, Canada, and the similar "tar sands" in Utah, US. The Canadian province of Alberta has most of the world's reserves, in three huge deposits covering 142,000 square kilometres (55,000 sq mi), an area larger than England or New York state. These bituminous sands contain 166 billion barrels (26.4×10^9 m3) of commercially established oil reserves, giving Canada the third largest oil reserves in the world. Although historically it was used without refining to pave roads, nearly all of the output is now used as raw material for oil refineries in Canada and the United States.[8]

The world's largest deposit of natural bitumen, known as the Athabasca oil sands, is located in the McMurray Formation of Northern Alberta. This formation is from the early Cretaceous, and is composed of numerous lenses of oil-bearing sand with up to 20% oil.[19] Isotopic studies show the oil deposits to be about 110 million years old.[20] Two smaller but still very large formations occur in the Peace River oil sands and the Cold Lake oil sands, to the west and southeast of the Athabasca oil sands, respectively. Of the Alberta deposits, only parts of the Athabasca oil sands are shallow enough to be suitable for surface mining. The other 80% has to be produced by oil wells using enhanced oil recovery techniques like steam-assisted gravity drainage.[21]

Much smaller heavy oil or bitumen deposits also occur in the Uinta Basin in Utah, US. The Tar Sand Triangle deposit, for example, is roughly 6% bitumen.[19]

Bitumen may occur in hydrothermal veins. An example of this is within the Uinta Basin of Utah, in the US, where there is a swarm of laterally and vertically extensive veins composed of a solid hydrocarbon termed Gilsonite. These veins formed by the polymerization and solidification of hydrocarbons that were mobilized from the deeper oil shales of the Green River Formation during burial and diagenesis.[22]

Bitumen is similar to the organic matter in carbonaceous meteorites.[23] However, detailed studies have shown these materials to be distinct.[24] The vast Alberta bitumen resources are considered to have started out as living material from marine plants and animals, mainly algae, that died millions of years ago when an ancient ocean covered Alberta. They were covered by mud, buried deeply over time, and gently cooked into oil by geothermal heat at a temperature of 50 to 150 °C (120 to 300 °F). Due to pressure from the rising of the Rocky Mountains in southwestern Alberta, 80 to 55 million years ago, the oil was driven northeast hundreds of kilometres and trapped into underground sand deposits left behind by ancient river beds and ocean beaches, thus forming the oil sands.[21]

The use of natural bitumen for waterproofing, and as an adhesive dates at least to the fifth millennium BC, with a crop storage basket discovered in Mehrgarh, of the Indus Valley Civilization, lined with it.[25] By the 3rd millennia BC refined rock asphalt was in use, in the region, and was used to waterproof the Great Bath, Mohenjo-daro.

In the ancient Middle East, the Sumerians used natural bitumen deposits for mortar between bricks and stones, to cement parts of carvings, such as eyes, into place, for ship caulking, and for waterproofing.[3] The Greek historian Herodotus said hot bitumen was used as mortar in the walls of Babylon.[26]

The 1 kilometre (0.62 mi) long Euphrates Tunnel beneath the river Euphrates at Babylon in the time of Queen Semiramis (ca. 800 BC) was reportedly constructed of burnt bricks covered with bitumen as a waterproofing agent.[27]

Bitumen was used by ancient Egyptians to embalm mummies.[3][28] The Persian word for asphalt is moom, which is related to the English word mummy. The Egyptians' primary source of bitumen was the Dead Sea, which the Romans knew as Palus Asphaltites (Asphalt Lake).

Approximately 40 AD, Dioscorides described the Dead Sea material as Judaicum bitumen, and noted other places in the region where it could be found.[29] The Sidon bitumen is thought to refer to material found at Hasbeya.[30] Pliny refers also to bitumen being found in Epirus. It was a valuable strategic resource, the object of the first known battle for a hydrocarbon deposit—between the Seleucids and the Nabateans in 312 BC.[31]

In the ancient Far East, natural bitumen was slowly boiled to get rid of the higher fractions, leaving a thermoplastic material of higher molecular weight that when layered on objects became quite hard upon cooling. This was used to cover objects that needed waterproofing,[3] such as scabbards and other items. Statuettes of household deities were also cast with this type of material in Japan, and probably also in China.

In North America, archaeological recovery has indicated bitumen was sometimes used to adhere stone projectile points to wooden shafts.[32] In Canada, aboriginal people used bitumen seeping out of the banks of the Athabasca and other rivers to waterproof birch bark canoes, and also heated it in smudge pots to ward off mosquitoes in the summer.[21]

In 1553, Pierre Belon described in his work Observations that pissasphalto, a mixture of pitch and bitumen, was used in the Republic of Ragusa (now Dubrovnik, Croatia) for tarring of ships.[33]

An 1838 edition of Mechanics Magazine cites an early use of asphalt in France. A pamphlet dated 1621, by "a certain Monsieur d'Eyrinys, states that he had discovered the existence (of asphaltum) in large quantities in the vicinity of Neufchatel", and that he proposed to use it in a variety of ways – "principally in the construction of air-proof granaries, and in protecting, by means of the arches, the water-courses in the city of Paris from the intrusion of dirt and filth", which at that time made the water unusable. "He expatiates also on the excellence of this material for forming level and durable terraces" in palaces, "the notion of forming such terraces in the streets not one likely to cross the brain of a Parisian of that generation".[34]

But the substance was generally neglected in France until the revolution of 1830. In the 1830s there was a surge of interest, and asphalt became widely used "for pavements, flat roofs, and the lining of cisterns, and in England, some use of it had been made of it for similar purposes". Its rise in Europe was "a sudden phenomenon", after natural deposits were found "in France at Osbann (Bas-Rhin), the Parc (Ain) and the Puy-de-la-Poix (Puy-de-Dôme)", although it could also be made artificially.[35] One of the earliest uses in France was the laying of about 24,000 square yards of Seyssel asphalt at the Place de la Concorde in 1835.[36]

Among the earlier uses of bitumen in the United Kingdom was for etching. William Salmon's Polygraphice (1673) provides a recipe for varnish used in etching, consisting of three ounces of virgin wax, two ounces of mastic, and one ounce of asphaltum.[37] By the fifth edition in 1685, he had included more asphaltum recipes from other sources.[38]

The first British patent for the use of asphalt was "Cassell's patent asphalte or bitumen" in 1834.[35] Then on 25 November 1837, Richard Tappin Claridge patented the use of Seyssel asphalt (patent #7849), for use in asphalte pavement,[39][40] having seen it employed in France and Belgium when visiting with Frederick Walter Simms, who worked with him on the introduction of asphalt to Britain.[41][42] Dr T. Lamb Phipson writes that his father, Samuel Ryland Phipson, a friend of Claridge, was also "instrumental in introducing the asphalte pavement (in 1836)".[43] Indeed, mastic pavements had been previously employed at Vauxhall by a competitor of Claridge, but without success.[36]

Claridge obtained a patent in Scotland on 27 March 1838, and obtained a patent in Ireland on 23 April 1838. In 1851, extensions for the 1837 patent and for both 1838 patents were sought by the trustees of a company previously formed by Claridge.[35][44][45][46] Claridge's Patent Asphalte Company—formed in 1838 for the purpose of introducing to Britain "Asphalte in its natural state from the mine at Pyrimont Seysell in France",[47]—"laid one of the first asphalt pavements in Whitehall".[48] Trials were made of the pavement in 1838 on the footway in Whitehall, the stable at Knightsbridge Barracks,[47][49] "and subsequently on the space at the bottom of the steps leading from Waterloo Place to St. James Park".[49] "The formation in 1838 of Claridge's Patent Asphalte Company (with a distinguished list of aristocratic patrons, and Marc and Isambard Brunel as, respectively, a trustee and consulting engineer), gave an enormous impetus to the development of a British asphalt industry".[45] "By the end of 1838, at least two other companies, Robinson's and the Bastenne company, were in production",[50] with asphalt being laid as paving at Brighton, Herne Bay, Canterbury, Kensington, the Strand, and a large floor area in Bunhill-row, while meantime Claridge's Whitehall paving "continue(d) in good order".[51]

In 1838, there was a flurry of entrepreneurial activity involving asphalt, which had uses beyond paving. For example, asphalt could also be used for flooring, damp proofing in buildings, and for waterproofing of various types of pools and baths, both of which were also proliferating in the 19th century.[3][35][52] On the London stockmarket, there were various claims as to the exclusivity of asphalt quality from France, Germany and England. And numerous patents were granted in France, with similar numbers of patent applications being denied in England due to their similarity to each other. In England, "Claridge's was the type most used in the 1840s and 50s".[50]

In 1914, Claridge's Company entered into a joint venture to produce tar-bound macadam,[53] with materials manufactured through a subsidiary company called Clarmac Roads Ltd.[54] Two products resulted, namely Clarmac, and Clarphalte, with the former being manufactured by Clarmac Roads and the latter by Claridge's Patent Asphalte Co., although Clarmac was more widely used.[55][note 1] However, the First World War ruined the Clarmac Company, which entered into liquidation in 1915.[57][58] The failure of Clarmac Roads Ltd had a flow-on effect to Claridge's Company, which was itself compulsorily wound up,[59] ceasing operations in 1917,[60][61] having invested a substantial amount of funds into the new venture, both at the outset[59] and in a subsequent attempt to save the Clarmac Company.[57]

The first use of bitumen in the New World was by indigenous peoples. On the west coast, as early as the 13th century, the Tongva, Luiseño and Chumash peoples collected the naturally occurring bitumen that seeped to the surface above underlying petroleum deposits. All three groups used the substance as an adhesive. It is found on many different artifacts of tools and ceremonial items. For example, it was used on rattles to adhere gourds or turtle shells to rattle handles. It was also used in decorations. Small round shell beads were often set in asphaltum to provide decorations. It was used as a sealant on baskets to make them watertight for carrying water, possibly poisoning those who drank the water.[62] Asphalt was used also to seal the planks on ocean-going canoes.

Asphalt was first used to pave streets in the 1870s. At first naturally occurring "bituminous rock" was used, such as at Ritchie Mines in Macfarlan in Ritchie County, West Virginia from 1852 to 1873. In 1876, asphalt-based paving was used to pave Pennsylvania Avenue in Washington DC, in time for the celebration of the national centennial.[63] In the horse-drawn era, streets were unpaved and covered with dirt or gravel. However, that produced uneven wear, opened new hazards for pedestrians and made for dangerous potholes for bicycles and for motor vehicles. Manhattan alone had 130,000 horses in 1900, pulling streetcars, wagons, and carriages, and leaving their waste behind. They were not fast, and pedestrians could dodge and scramble their way across the crowded streets. Small towns continued to rely on dirt and gravel, but larger cities wanted much better streets. They looked to wood or granite blocks by the 1850s.[64] In 1890, a third of Chicago's 2000 miles of streets were paved, chiefly with wooden blocks, which gave better traction than mud. Brick surfacing was a good compromise, but even better was asphalt paving, which was easy to install and to cut through to get at sewers. With London and Paris serving as models, Washington laid 400,000 square yards of asphalt paving by 1882; it became the model for Buffalo, Philadelphia and elsewhere. By the end of the century, American cities boasted 30 million square yards of asphalt paving, well ahead of brick.[65] The streets became faster and more dangerous so electric traffic lights were installed. Electric trolleys (at 12 miles per hour) became the main transportation service for middle class shoppers and office workers until they bought automobiles after 1945 and commuted from more distant suburbs in privacy and comfort on asphalt highways.[66]

See also: Bitumount and History of the petroleum industry in Canada (oil sands and heavy oil)

Canada has the world's largest deposit of natural bitumen in the Athabasca oil sands, and Canadian First Nations along the Athabasca River had long used it to waterproof their canoes. In 1719, a Cree named Wa-Pa-Su brought a sample for trade to Henry Kelsey of the Hudson’s Bay Company, who was the first recorded European to see it. However, it wasn't until 1787 that fur trader and explorer Alexander MacKenzie saw the Athabasca oil sands and said, "At about 24 miles from the fork (of the Athabasca and Clearwater Rivers) are some bituminous fountains into which a pole of 20 feet long may be inserted without the least resistance."[21]

The value of the deposit was obvious from the start, but the means of extracting the bitumen was not. The nearest town, Fort McMurray, Alberta, was a small fur trading post, other markets were far away, and transportation costs were too high to ship the raw bituminous sand for paving. In 1915, Sidney Ells of the Federal Mines Branch experimented with separation techniques and used the product to pave 600 feet of road in Edmonton, Alberta. Other roads in Alberta were paved with material extracted from oil sands, but it was generally not economic. During the 1920s Dr. Karl A. Clark of the Alberta Research Council patented a hot water oil separation process and entrepreneur Robert C. Fitzsimmons[67] built the Bitumount oil separation plant, which between 1925 and 1958 produced up to 300 barrels (50 m3) per day of bitumen using Dr. Clark's method. Most of the bitumen was used for waterproofing roofs, but other uses included fuels, lubrication oils, printers ink, medicines, rust- and acid-proof paints, fireproof roofing, street paving, patent leather, and fence post preservatives.[21] Eventually Fitzsimmons ran out of money and the plant was taken over by the Alberta government. Today the Bitumount plant is a Provincial Historic Site.[68]

Bitumen was used in early photographic technology. In 1826 or 1827, it was used by French scientist Joseph Nicéphore Niépce to make the oldest surviving photograph from nature. The bitumen was thinly coated onto a pewter plate which was then exposed in a camera. Exposure to light hardened the bitumen and made it insoluble, so that when it was subsequently rinsed with a solvent only the sufficiently light-struck areas remained. Many hours of exposure in the camera were required, making bitumen impractical for ordinary photography, but from the 1850s to the 1920s it was in common use as a photoresist in the production of printing plates for various photomechanical printing processes.[69][70]

Bitumen was the nemesis of many artists during the 19th century. Although widely used for a time, it ultimately proved unstable for use in oil painting, especially when mixed with the most common diluents, such as linseed oil, varnish and turpentine. Unless thoroughly diluted, bitumen never fully solidifies and will in time corrupt the other pigments with which it comes into contact. The use of bitumen as a glaze to set in shadow or mixed with other colors to render a darker tone resulted in the eventual deterioration of many paintings, for instance those of Delacroix. Perhaps the most famous example of the destructiveness of bitumen is Théodore Géricault's Raft of the Medusa (1818–1819), where his use of bitumen caused the brilliant colors to degenerate into dark greens and blacks and the paint and canvas to buckle.[71]

The vast majority of refined asphalt is used in construction: primarily as a constituent of products used in paving and roofing applications. According to the requirements of the end use, asphalt is produced to specification. This is achieved either by refining or blending. It is estimated that the current world use of asphalt is approximately 102 million tonnes per year. Approximately 85% of all the asphalt produced is used as the binder in asphalt concrete for roads. It is also used in other paved areas such as airport runways, car parks and footways. Typically, the production of asphalt concrete involves mixing fine and coarse aggregates such as sand, gravel and crushed rock with asphalt, which acts as the binding agent. Other materials, such as recycled polymers (e.g., rubber tyres), may be added to the asphalt to modify its properties according to the application for which the asphalt is ultimately intended.

A further 10% of global asphalt production is used in roofing applications, where its waterproofing qualities are invaluable. The remaining 5% of asphalt is used mainly for sealing and insulating purposes in a variety of building materials, such as pipe coatings, carpet tile backing and paint. Asphalt is applied in the construction and maintenance of many structures, systems, and components, such as the following:

Main article: Asphalt concrete

The largest use of asphalt is for making asphalt concrete for road surfaces; this accounts for approximately 85% of the asphalt consumed in the United States. Asphalt concrete pavement mixes are typically composed of 5% asphalt cement and 95% aggregates (stone, sand, and gravel). Due to its highly viscous nature, asphalt cement must be heated so it can be mixed with the aggregates at the asphalt mixing facility. The temperature required varies depending upon characteristics of the asphalt and the aggregates, but warm-mix asphalt technologies allow producers to reduce the temperature required. There are about 4,000 asphalt concrete mixing plants in the US, and a similar number in Europe.[72]

When maintenance is performed on asphalt pavements, such as milling to remove a worn or damaged surface, the removed material can be returned to a facility for processing into new pavement mixtures. The asphalt in the removed material can be reactivated and put back to use in new pavement mixes.[73] With some 95% of paved roads being constructed of or surfaced with asphalt,[74] a substantial amount of asphalt pavement material is reclaimed each year. According to industry surveys conducted annually by the Federal Highway Administration and the National Asphalt Pavement Association, more than 99% of the asphalt removed each year from road surfaces during widening and resurfacing projects is reused as part of new pavements, roadbeds, shoulders and embankments.[75]

Asphalt concrete paving is widely used in airports around the world. Due to the sturdiness and ability to be repaired quickly, it is widely used for runways.

Further information: Fibre mastic asphalt

Mastic asphalt is a type of asphalt that differs from dense graded asphalt (asphalt concrete) in that it has a higher asphalt (binder) content, usually around 7–10% of the whole aggregate mix, as opposed to rolled asphalt concrete, which has only around 5% asphalt. This thermoplastic substance is widely used in the building industry for waterproofing flat roofs and tanking underground. Mastic asphalt is heated to a temperature of 210 °C (410 °F) and is spread in layers to form an impervious barrier about 20 millimeters (0.8 inches) thick.

A number of technologies allow asphalt to be mixed at much lower temperatures. These involve mixing with petroleum solvents to form "cutbacks" with reduced melting point or mixing with water to turn the asphalt into an emulsion. Asphalt emulsions contain up to 70% asphalt and typically less than 1.5% chemical additives. There are two main types of emulsions with different affinity for aggregates, cationic and anionic. Asphalt emulsions are used in a wide variety of applications. Chipseal involves spraying the road surface with asphalt emulsion followed by a layer of crushed rock, gravel or crushed slag. Slurry seal involves the creation of a mixture of asphalt emulsion and fine crushed aggregate that is spread on the surface of a road. Cold-mixed asphalt can also be made from asphalt emulsion to create pavements similar to hot-mixed asphalt, several inches in depth, and asphalt emulsions are also blended into recycled hot-mix asphalt to create low-cost pavements.

Main article: Synthetic crude oil See also: Petroleum production in Canada

Synthetic crude oil, also known as syncrude, is the output from a bitumen upgrader facility used in connection with oil sand production in Canada. Bituminous sands are mined using enormous (100 ton capacity) power shovels and loaded into even larger (400 ton capacity) dump trucks for movement to an upgrading facility. The process used to extract the bitumen from the sand is a hot water process originally developed by Dr. Karl Clark of the University of Alberta during the 1920s. After extraction from the sand, the bitumen is fed into a bitumen upgrader which converts it into a light crude oil equivalent. This synthetic substance is fluid enough to be transferred through conventional oil pipelines and can be fed into conventional oil refineries without any further treatment. By 2015 Canadian bitumen upgraders were producing over 1 million barrels (160×10^3 m3) per day of synthetic crude oil, of which 75% was exported to oil refineries in the United States.[76]

In Alberta, five bitumen upgraders produce synthetic crude oil and a variety of other products: The Suncor Energy upgrader near Fort McMurray, Alberta produces synthetic crude oil plus diesel fuel; the Syncrude Canada, Canadian Natural Resources, and Nexen upgraders near Fort McMurray produce synthetic crude oil; and the Shell Scotford Upgrader near Edmonton produces synthetic crude oil plus an intermediate feedstock for the nearby Shell Oil Refinery.[77] A sixth upgrader, under construction in 2015 near Redwater, Alberta, will upgrade half of its crude bitumen directly to diesel fuel, with the remainder of the output being sold as feedstock to nearby oil refineries and petrochemical plants.[78]

See also: Western Canadian Select

Canadian bitumen does not differ substantially from oils such as Venezuelan extra-heavy and Mexican heavy oil in chemical composition, and the real difficulty is moving the extremely viscous bitumen through oil pipelines to the refinery. Many modern oil refineries are extremely sophisticated and can process non-upgraded bitumen directly into products such as gasoline, diesel fuel, and refined asphalt without any preprocessing. This is particularly common in areas such as the US Gulf coast, where refineries were designed to process Venezuelan and Mexican oil, and in areas such as the US Midwest where refineries were rebuilt to process heavy oil as domestic light oil production declined. Given the choice, such heavy oil refineries usually prefer to buy bitumen rather than synthetic oil because the cost is lower, and in some cases because they prefer to produce more diesel fuel and less gasoline.[77] By 2015 Canadian production and exports of non-upgraded bitumen exceeded that of synthetic crude oil at over 1.3 million barrels (210×10^3 m3) per day, of which about 65% was exported to the United States.[76]

Because of the difficulty of moving crude bitumen through pipelines, non-upgraded bitumen is usually diluted with natural-gas condensate in a form called dilbit or with synthetic crude oil, called synbit. However, to meet international competition, much non-upgraded bitumen is now sold as a blend of multiple grades of bitumen, conventional crude oil, synthetic crude oil, and condensate in a standardized benchmark product such as Western Canadian Select. This sour, heavy crude oil blend is designed to have uniform refining characteristics to compete with internationally marketed heavy oils such as Mexican Mayan or Arabian Dubai Crude.[77]

Asphalt was used starting in the 1960s as an hydrophobic matrix aiming to encapsulate radioactive waste such as medium-activity salts (mainly soluble sodium nitrate and sodium sulfate) produced by the reprocessing of spent nuclear fuels or radioactive sludges from sedimentation ponds.[79][80] Bituminised radioactive waste containing highly radiotoxic alpha-emitting transuranic elements from nuclear reprocessing plants have been produced at industrial scale in France, Belgium and Japan, but this type of waste conditioning has been abandoned because operational safety issues (risks of fire, as occurred in a bituminisation plant at Tokai Works in Japan)[81][82] and long-term stability problems related to their geological disposal in deep rock formations. One of the main problem is the swelling of asphalt exposed to radiation and to water. Asphalt swelling is first induced by radiation because of the presence of hydrogen gas bubbles generated by alpha and gamma radiolysis.[83][84] A second mechanism is the matrix swelling when the encapsulated hygroscopic salts exposed to water or moisture start to rehydrate and to dissolve. The high concentration of salt in the pore solution inside the bituminised matrix is then responsible for osmotic effects inside the bituminised matrix. The water moves in the direction of the concentrated salts, the asphalt acting as a semi-permeable membrane. This also causes the matrix to swell. The swelling pressure due to osmotic effect under constant volume can be as high as 200 bar. If not properly managed, this high pressure can cause fractures in the near field of a disposal gallery of bituminised medium-level waste. When the bituminised matrix has been altered by swelling, encapsulated radionuclides are easily leached by the contact of ground water and released in the geosphere. The high ionic strength of the concentrated saline solution also favours the migration of radionuclides in clay host rocks. The presence of chemically reactive nitrate can also affect the redox conditions prevailing in the host rock by establishing oxidizing conditions, preventing the reduction of redox-sensitive radionuclides. Under their higher valences, radionuclides of elements such as selenium, technetium, uranium, neptunium and plutonium have a higher solubility and are also often present in water as non-retarded anions. This makes the disposal of medium-level bituminised waste very challenging.

Different type of asphalt have been used: blown bitumen (partly oxidized with air oxygen at high temperature after distillation, and harder) and direct distillation bitumen (softer). Blown bitumens like Mexphalte, with a high content of saturated hydrocarbons, are more easily biodegraded by microorganisms than direct distillation bitumen, with a low content of saturated hydrocarbons and a high content of aromatic hydrocarbons.[85]

Concrete encapsulation of radwaste is presently considered a safer alternative by the nuclear industry and the waste management organisations.

Roofing shingles account for most of the remaining asphalt consumption. Other uses include cattle sprays, fence-post treatments, and waterproofing for fabrics. Asphalt is used to make Japan black, a lacquer known especially for its use on iron and steel, and it is also used in paint and marker inks by some exterior paint supply companies to increase the weather resistance and permanence of the paint or ink, and to make the color darker.[86] Asphalt is also used to seal some alkaline batteries during the manufacturing process.

Typical asphalt plant for making asphalt

About 40,000,000 tons were produced in 1984.[needs update] It is obtained as the "heavy" (i.e., difficult to distill) fraction. Material with a boiling point greater than around 500 °C is considered asphalt. Vacuum distillation separates it from the other components in crude oil (such as naphtha, gasoline and diesel). The resulting material is typically further treated to extract small but valuable amounts of lubricants and to adjust the properties of the material to suit applications. In a de-asphalting unit, the crude asphalt is treated with either propane or butane in a supercritical phase to extract the lighter molecules, which are then separated. Further processing is possible by "blowing" the product: namely reacting it with oxygen. This step makes the product harder and more viscous.[5]

Asphalt is typically stored and transported at temperatures around 150 °C (302 °F). Sometimes diesel oil or kerosene are mixed in before shipping to retain liquidity; upon delivery, these lighter materials are separated out of the mixture. This mixture is often called "bitumen feedstock", or BFS. Some dump trucks route the hot engine exhaust through pipes in the dump body to keep the material warm. The backs of tippers carrying asphalt, as well as some handling equipment, are also commonly sprayed with a releasing agent before filling to aid release. Diesel oil is no longer used as a release agent due to environmental concerns.

Main article: Oil sands

Naturally occurring crude bitumen impregnated in sedimentary rock is the prime feed stock for petroleum production from "oil sands", currently under development in Alberta, Canada. Canada has most of the world's supply of natural bitumen, covering 140,000 square kilometres[14] (an area larger than England), giving it the second-largest proven oil reserves in the world. The Athabasca oil sands are the largest bitumen deposit in Canada and the only one accessible to surface mining, although recent technological breakthroughs have resulted in deeper deposits becoming producible by in situ methods. Because of oil price increases after 2003, producing bitumen became highly profitable, but as a result of the decline after 2014 it became uneconomic to build new plants again. By 2014, Canadian crude bitumen production averaged about 2.3 million barrels (370,000 m3) per day and was projected to rise to 4.4 million barrels (700,000 m3) per day by 2020.[15] The total amount of crude bitumen in Alberta that could be extracted is estimated to be about 310 billion barrels (50×10^9 m3),[8] which at a rate of 4,400,000 barrels per day (700,000 m3/d) would last about 200 years.

Main articles: Peak oil, Global warming, and Bioasphalt

Although uncompetitive economically, asphalt can be made from nonpetroleum-based renewable resources such as sugar, molasses and rice, corn and potato starches. Asphalt can also be made from waste material by fractional distillation of used motor oil, which is sometimes otherwise disposed of by burning or dumping into landfills. Use of motor oil may cause premature cracking in colder climates, resulting in roads that need to be repaved more frequently.[87]

Nonpetroleum-based asphalt binders can be made light-colored. Lighter-colored roads absorb less heat from solar radiation, reducing their contribution to the urban heat island effect.[88] Parking lots that use asphalt alternatives are called green parking lots.

Selenizza is a naturally occurring solid hydrocarbon bitumen found in native deposits in Selenice, in Albania, the only European asphalt mine still in use. The bitumen is found in the form of veins, filling cracks in a more or less horizontal direction. The bitumen content varies from 83% to 92% (soluble in carbon disulphide), with a penetration value near to zero and a softening point (ring and ball) around 120 °C. The insoluble matter, consisting mainly of silica ore, ranges from 8% to 17%.

Albanian bitumen extraction has a long history and was practiced in an organized way by the Romans. After centuries of silence, the first mentions of Albanian bitumen appeared only in 1868, when the Frenchman Coquand published the first geological description of the deposits of Albanian bitumen. In 1875, the exploitation rights were granted to the Ottoman government and in 1912, they were transferred to the Italian company Simsa. Since 1945, the mine was exploited by the Albanian government and from 2001 to date, the management passed to a French company, which organized the mining process for the manufacture of the natural bitumen on an industrial scale.[89]

Today the mine is predominantly exploited in an open pit quarry but several of the many underground mines (deep and extending over several km) still remain viable. Selenizza is produced primarily in granular form, after melting the bitumen pieces selected in the mine.

Selenizza[90] is mainly used as an additive in the road construction sector. It is mixed with traditional asphalt to improve both the viscoelastic properties and the resistance to ageing. It may be blended with the hot asphalt in tanks, but its granular form allows it to be fed in the mixer or in the recycling ring of normal asphalt plants. Other typical applications include the production of mastic asphalts for sidewalks, bridges, car-parks and urban roads as well as drilling fluid additives for the oil and gas industry. Selenizza is available in powder or in granular material of various particle sizes and is packaged in sacks or in thermal fusible polyethylene bags.

A life-cycle assessment study of the natural selenizza compared with petroleum asphalt has shown that the environmental impact of the selenizza is about half the impact of the road asphalt produced in oil refineries in terms of carbon dioxide emission.[91]

People can be exposed to asphalt in the workplace by breathing in fumes or skin absorption. The National Institute for Occupational Safety and Health (NIOSH) has set a recommended exposure limit of 5 mg/m3 over a 15-minute period.[92]

Asphalt is basically an inert material that must be heated or diluted to a point where it becomes workable for the production of materials for paving, roofing, and other applications. In examining the potential health hazards associated with asphalt, the International Agency for Research on Cancer (IARC) determined that it is the application parameters, predominantly temperature, that affect occupational exposure and the potential bioavailable carcinogenic hazard/risk of the asphalt emissions.[93] In particular, temperatures greater than 199 °C (390 °F), were shown to produce a greater exposure risk than when asphalt was heated to lower temperatures, such as those typically used in asphalt pavement mix production and placement.[94] IARC has classified asphalt as a Class 2B possible carcinogen.

An asphalt mixing plant for hot aggregate
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  38. ^ Salmon, William (1685), Polygraphice; Or, The Arts of Drawing, Engraving, Etching, Limning, Painting, Washing, Varnishing, Gilding, Colouring, Dying, Beautifying and Perfuming (5th ed.), London: R. Jones, pp. 76–77, retrieved 18 August 2010  Text at Internet Archive
  39. ^ "Specification of the Patent granted to Richard Tappin Claridge, of the County of Middlesex, for a Mastic Cement, or Composition applicable to Paving and Road making, covering Buildings and various purposes". Journal of the Franklin Institute of the State of Pennsylvania and Mechanics' Register. Vol. 22. London: Pergamon Press. July 1838. pp. 414–418. Retrieved 18 November 2009. 
  40. ^ "Comments on asphalt patents of R.T. Claridge, Esq". Notes and Queries: A medium of intercommunication for Literary Men, General Readers, etc. Ninth series. Volume XII, July–December, 1903 (9th S. XII, 4 July 1903). London: John C. Francis. 20 January 1904. pp. 18–19.  Writer is replying to note or query from previous publication, cited as 9th S. xi. 30
  41. ^ "Obituary of Frederick Walter Simms". Monthly Notices of the Royal Astronomical Society. London: Strangeways & Walden. XXVI: 120–121. November 1865 – June 1866. Retrieved 12 November 2009. 
  42. ^ Broome, D.C. (1963). "The development of the modern asphalt road". The Surveyor and municipal and county engineer. London. 122 (3278 & 3279): 1437–1440 & 1472–1475Snippet view: Simms & Claridge p.1439 
  43. ^ Phipson, Dr T. Lamb (1902). Confessions of a Violinist: Realities and Romance. London: Chatto & Windus. p. 11. Retrieved 26 November 2009.  Full text at Internet Archive (archive.org)
  44. ^ "Claridge's UK Patents in 1837 & 1838". The London Gazette. 25 February 1851. p. 489. 
  45. ^ a b Hobhouse, Hermione (General Editor) (1994). "British History Online". 'Northern Millwall: Tooke Town', Survey of London: volumes 43 and 44: Poplar, Blackwall and Isle of Dogs. pp. 423–433 (see text at refs 169 & 170). Retrieved 8 November 2009. 
  46. ^ "Claridge's Scottish and Irish Patents in 1838". The Mechanic's magazine, museum, register, journal and gazette. 29. London: W.A. Robertson. 7 April – 29 September 1838. pp. vii, viii, 64, 128. 
  47. ^ a b "Joint Stock Companies (description of asphalte use by Claridge's company)". The Civil Engineer and Architects Journal. Vol. 1. London. October 1837 – December 1838. p. 199. Retrieved 16 November 2009.  Full text at Internet Archive (archive.org). Alternative viewing at: https://books.google.com/books?id=sQ5AAAAAYAAJ&pg
  48. ^ Miles, Lewis (2000), pp.10.06.1–2
  49. ^ a b Comments on asphalt patents of R.T. Claridge, Esq (1904), p.18
  50. ^ a b Miles, Lewis (2000), p.10.06.2
  51. ^ "1838 bitumen UK uses by Robinson's and Claridge's companies, & the Bastenne company". The Mechanic's magazine, museum, register, journal and gazette. 29. London: W.A. Robertson. 22 September 1838. p. 448. 
  52. ^ Gerhard, W.M. Paul (1908). Modern Baths and Bath Houses (1st ed.). New York: John Wiley and Sons.  (Enter "asphalt" into the search field for list of pages discussing the subject)
  53. ^ "Claridge's Patent Asphalte Co. ventures into tarred slag macadam", Concrete and Constructional Engineering, London, IX (1): 760, January 1914, retrieved 15 June 2010 
  54. ^ "Registration of Clarmac Roads", The Law Reports: Chancery Division, Vol. 1: 544–547, 1921, retrieved 17 June 2010 
  55. ^ "Clarmac and Clarphalte", The Building News and Engineering Journal, Vol. 109: July to December 1915 (No. 3157): 2–4 (n13–15 in electronic page field), 7 July 1915, retrieved 18 June 2010 
  56. ^ Roads laid with Clarmac The Building News and Engineering Journal, 1915 109 (3157), p.3 (n14 in electronic field).
  57. ^ a b Clarmac financial difficults due to WW1 Debentures deposited The Law Reports: Chancery Division, (1921) Vol. 1 p.545. Retrieved 17 June 2010.
  58. ^ "Notice of the Winding up of Clarmac Roads", The London Gazette (29340): 10568, 26 October 1915, retrieved 15 June 2010 
  59. ^ a b Claridge's Patent Asphalte Co. compulsorily wound up Funds invested in new company The Law Times Reports (1921) Vol.125, p.256. Retrieved 15 June 2010.
  60. ^ "Claridge's Patent Asphalte Co. winds up 10 November 1917". The London Gazette. 16 November 1917. p. 11863. 
  61. ^ Hobhouse, Hermione (General Editor) (1994). "British History Online". 'Cubitt Town: Riverside area: from Newcastle Drawdock to Cubitt Town Pier', Survey of London: volumes 43 and 44: Poplar, Blackwall and Isle of Dogs. pp. 528–532 (see text at refs 507 & 510). Retrieved 8 November 2009. 
  62. ^ Stockton, Nick (23 June 2017). "Plastic Water Bottles Might Have Poisoned Ancient Californians". Wired. Retrieved 26 June 2017. 
  63. ^ McNichol, Dan (2005). Paving the Way: Asphalt in America. Lanham, MD: National Asphalt Pavement Association. ISBN 0-914313-04-5. Archived from the original on 2006-08-29. 
  64. ^ David O. Whitten, "A Century of Parquet Pavements: Wood as a Paving Material In The United States And Abroad, 1840-1940." Essays in Economic and Business History 15 (1997): 209-26.
  65. ^ Arthur Maier Schlesinger, The Rise of the City: 1878-1898 (1933) p 88-93.
  66. ^ John D. Fairfield, "Rapid Transit: Automobility and Settlement in Urban America" Reviews in American History 23#1 (1995), pp. 80-85 online.
  67. ^ "Robert C. Fitzsimmons (1881–1971)". Canadian Petroleum Hall of Fame. 2010. Retrieved 2016-01-20. 
  68. ^ "Bitumount". Government of Alberta. 2016. Retrieved 2016-01-20. 
  69. ^ Niépce Museum history pages. Retrieved 27 October 2012. Archived 3 August 2007 at the Wayback Machine.
  70. ^ The First Photograph (Harry Ransom Center, University of Texas at Austin). Retrieved 27 October 2012.
  71. ^ Spiegelman, Willard (2009-08-21). "Revolutionary Romanticism: 'The Raft of the Medusa' brought energy to French art". The Wall Street Journal. New York City. Retrieved 2016-01-27. 
  72. ^ The Asphalt Paving Industry: A Global Perspective, 2nd Edition (PDF). Lanham, Maryland, and Brussels: National Asphalt Pavement Association and European Asphalt Pavement Association. February 2011. ISBN 0-914313-06-1. Retrieved 27 September 2012. 
  73. ^ "How Should We Express RAP and RAS Contents?". Asphalt Technology E-News. 26 (2). 2014. Archived from the original on 9 June 2015. Retrieved 2015-08-13. 
  74. ^ "Highway Statistics Series: Public Road Length Miles by Type of Surface and Ownership". Federal Highway Administration. 2013-10-01. Retrieved 2015-08-13. 
  75. ^ "Asphalt Pavement Recycling". Annual Asphalt Pavement Industry Survey on Recycled Materials and Warm-Mix Asphalt Usage: 2009–2013. National Asphalt Pavement Association. Retrieved 13 August 2015. 
  76. ^ a b "Crude Oil and Petroleum Products". National Energy Board of Canada. Retrieved January 21, 2016. 
  77. ^ a b c "2015 CAPP Crude Oil Forecast, Markets & Transportation". Canadian Association of Petroleum Producers. Archived from the original on 20 January 2016. Retrieved January 21, 2016. 
  78. ^ "The Project". North West Redwater Partnership. Retrieved January 21, 2016. 
  79. ^ Rodier, J., Scheidhauer, J., & Malabre, M. (1961). The conditioning of radioactive waste by bitumen (No. CEA-R—1992). CEA Marcoule.
  80. ^ Lefillatre, G., Rodier, J., Hullo, R., Cudel, Y., & Rodi, L. (1969). Use of a thin-film evaporator for bitumen coating of radioactive concentrates (No. CEA-R—3742). CEA Marcoule.
  81. ^ Sato, Y., Miura, A., Kato, Y., Suzuki, H., Shigetome, Y., Koyama, T., ... & Yamanouchi, T. (2000). Study on the cause of the fire and explosion incident at Bituminization Demonstration Facility of PNC Tokai Works. In Nuclear waste: from research to industrial maturity. International conference (pp. 179–190).
  82. ^ Okada, K., Nur, R. M., & Fujii, Y. (1999). The formation of explosive compounds in bitumen/nitrate mixtures. Journal of hazardous materials, 69(3), 245–256.
  83. ^ Johnson, D.I., Hitchon, J.W., & Phillips, D.C. (1986). Further observations of the swelling of bitumens and simulated bitumen wasteforms during γ-irradiation (No. AERE-R—12292). UKAEA Harwell Lab. Materials Development Division.
  84. ^ Phillips, D. C., Hitchon, J. W., Johnson, D. I., & Matthews, J. R. (1984). The radiation swelling of bitumens and bitumenised wastes. Journal of nuclear materials, 125(2), 202–218.
  85. ^ Ait-Langomazino, N., Sellier, R., Jouquet, G., & Trescinski, M. (1991). Microbial degradation of bitumen. Experientia, 47(6), 533–539.
  86. ^ Mohd, Meraj Jafri; Singh, D. K. (march 2013). "Cashew Nutshell Liquid Resin" (PDF). IJRREST: International Journal of Research Review in Engineering Science and Technology. 2: 60–65.  Check date values in: |date= (help)
  87. ^ Hesp, Simon A.M.; Herbert F. Shurvell (2010). "X-ray fluorescence detection of waste engine oil residue in asphalt and its effect on cracking in service". International Journal of Pavement Engineering. 11 (6): 541–553. doi:10.1080/10298436.2010.488729. ISSN 1029-8436. Retrieved 2014-03-24. 
  88. ^ Heat Island Effect. From the website of the US Environmental Protection Agency.
  89. ^ Giavarini, Carlo (March 2013). Six Thousand Years of Asphalt. SITEB. pp. 71–78. ISBN 978-88-908408-3-8. 
  90. ^ [3], Selenice Bitumi for more information about Selenizza
  91. ^ Giavarini, C.; Pellegrini, A. "Life cycle assessment of Selenice asphalt compared with petroleum bitumen". The 1st Albanian Congress on Roads: 234–237. 
  92. ^ "CDC – NIOSH Pocket Guide to Chemical Hazards – Asphalt fumes". www.cdc.gov. Retrieved 2015-11-27. 
  93. ^ IARC (2013). Bitumens and Bitumen Emissions, and Some N- and S-Heterocyclic Polycyclic Aromatic Hydrocarbons. 103. Lyon, France: International Agency for Research on Cancer. ISBN 978-92-832-1326-0. Retrieved 2015-12-07. 
  94. ^ Cavallari, J. M.; Zwack, L. M.; Lange, C. R.; Herrick, R. F.; Mcclean, M. D. (2012). "Temperature-Dependent Emission Concentrations of Polycyclic Aromatic Hydrocarbons in Paving and Built-Up Roofing Asphalts". Annals of Occupational Hygiene. 56 (2): 148–160. doi:10.1093/annhyg/mer107 . ISSN 0003-4878. 
  95. ^ "Contacto – Eco Roofing". epdmecoroofing.com. 
  96. ^ "Follow the evolution of the road from path to pavement". 


Driveway

Asphalt Contractors Near Me A high-speed toll booth on SR 417 near Orlando, Florida, United States. A toll collection area in the United Kingdom. Hong Kong toll booth.

A toll road, also known as a turnpike or tollway, is a public or private road for which a fee (or toll) is assessed for passage. It is a form of road pricing typically implemented to help recoup the cost of road construction and maintenance.

Toll roads have existed in some form since antiquity, with tolls levied on passing travellers on foot, wagon or horseback; but their prominence increased with the rise of the automobile,[citation needed] and many modern tollways charge fees for motor vehicles exclusively. The amount of the toll usually varies by vehicle type, weight, or number of axles, with freight trucks often charged higher rates than cars.

Tolls are often collected at toll booths, toll houses, plazas, stations, bars, or gates. Some toll collection points are unmanned and the user deposits money in a machine which opens the gate once the correct toll has been paid. To cut costs and minimise time delay many tolls today are collected by some form of automatic or electronic toll collection equipment which communicates electronically with a toll payer's transponder. Some electronic toll roads also maintain a system of toll booths so people without transponders can still pay the toll, but many newer roads now use automatic number plate recognition to charge drivers who use the road without a transponder, and some older toll roads are being upgraded with such systems.

Criticisms of toll roads include the time taken to stop and pay the toll, and the cost of the toll booth operators—up to about one third of revenue in some cases. Automated toll paying systems help minimise both of these. Others object to paying "twice" for the same road: in fuel taxes and with tolls.

In addition to toll roads, toll bridges and toll tunnels are also used by public authorities to generate funds to repay the cost of building the structures. Some tolls are set aside to pay for future maintenance or enhancement of infrastructure, or are applied as a general fund by local governments, not being earmarked for transport facilities. This is sometimes limited or prohibited by central government legislation. Also road congestion pricing schemes have been implemented in a limited number of urban areas as a transportation demand management tool to try to reduce traffic congestion and air pollution.[1]

A table of tolls in pre-decimal currency for the College Road, Dulwich, London SE21 tollgate.

Toll roads have existed for at least the last 2,700 years, as tolls had to be paid by travellers using the Susa–Babylon highway under the regime of Ashurbanipal, who reigned in the 7th century BC.[2] Aristotle and Pliny refer to tolls in Arabia and other parts of Asia. In India, before the 4th century BC, the Arthashastra notes the use of tolls. Germanic tribes charged tolls to travellers across mountain passes.

A 14th-century example (though not for a road) is Castle Loevestein in the Netherlands, which was built at a strategic point where two rivers meet. River tolls were charged on boats sailing along the river. The Øresund in Scandinavia was once subject to a toll to the Danish Monarch, which once provided a sizable portion of the king's revenue.

Many modern European roads were originally constructed as toll roads in order to recoup the costs of construction, maintenance and as a source of tax money that is paid primarily by someone other than the local residents. In 14th-century England, some of the most heavily used roads were repaired with money raised from tolls by pavage grants. Widespread toll roads sometimes restricted traffic so much, by their high tolls, that they interfered with trade and cheap transportation needed to alleviate local famines or shortages.[3]

Tolls were used in the Holy Roman Empire in the 14th and 15th centuries.

Industrialisation in Europe needed major improvements to the transport infrastructure which included many new or substantially improved roads, financed from tolls. The A5 road in Britain was built to provide a robust transport link between Britain and Ireland and had a toll house every few miles.

In the 20th century, road tolls were introduced in Europe to finance the construction of motorway networks and specific transport infrastructure such as bridges and tunnels. Italy was the first European country to charge motorway tolls, on a 50 km motorway section near Milan in 1924. It was followed by Greece, which made users pay for the network of motorways around and between its cities in 1927. Later in the 1950s and 1960s, France, Spain and Portugal started to build motorways largely with the aid of concessions, allowing rapid development of this infrastructure without massive State debts. Since then, road tolls have been introduced in the majority of the EU Member States.[4]

In the United States, prior to the introduction of the Interstate Highway System and the large federal grants supplied to states to build it, many states constructed their first controlled-access highways by floating bonds backed by toll revenues. Starting with the Pennsylvania Turnpike in 1940, and followed by similar roads in New Jersey (Garden State Parkway (1946) and New Jersey Turnpike, 1952), New York (New York State Thruway, 1954), Massachusetts (Massachusetts Turnpike, 1957), and others, numerous states throughout the 1950s established major toll roads. With the establishment of the Interstate Highway System in the late 1950s, toll road construction in the U.S. slowed down considerably, as the federal government now provided the bulk of funding to construct new freeways, and regulations required that such Interstate highways be free from tolls. Many older toll roads were added to the Interstate System under a grandfather clause that allowed tolls to continue to be collected on toll roads that predated the system. Some of these such as the Connecticut Turnpike and the Richmond–Petersburg Turnpike later removed their tolls when the initial bonds were paid off. Many states, however, have maintained the tolling of these roads, however, as a consistent source of revenue.

As the Interstate Highway System approached completion during the 1980s, states began constructing toll roads again to provide new controlled-access highways which were not part of the original interstate system funding. Houston's outer beltway of interconnected toll roads began in 1983, and many states followed over the last two decades of the 20th century adding new toll roads, including the tollway system around Orlando, Florida, Colorado's E-470, and Georgia State Route 400.

London, in an effort to reduce traffic within the city, instituted the London congestion charge in 2003, effectively making all roads within the city tolled.

In the United States, as states looked for ways to construct new freeways without federal funding again, to raise revenue for continued road maintenance, and to control congestion, new toll road construction saw significant increases during the first two decades of the 21st century. Spurred on by two innovations, the electronic toll collection system, and the advent of high occupancy and express lane tolls, many areas of the U.S saw large road building projects in major urban areas. Electronic toll collection, first introduced in the 1980s, reduces operating costs by removing toll collectors from roads. Tolled express lanes, by which certain lanes of a freeway are designated "toll only", increases revenue by allowing a free-to-use highway collect revenue by allowing drivers to bypass traffic jams by paying a toll. The E-ZPass system, compatible with many state systems, is the largest ETC system in the U.S., and is used for both fully tolled highways and tolled express lanes. Maryland Route 200 and the Triangle Expressway in North Carolina were the first toll roads built without toll booths, with drivers charged via ETC or by optical license plate recognition and are billed by mail.

19th-century toll booth in Brooklyn, New York Toll bar in Romania, 1877 Plaque commemorating the suppression of toll on a York bridge in 1914. Main article: Toll roads in Great Britain

Turnpike trusts were established in England and Wales from about 1706 in response to the need for better roads than the few and poorly-maintained tracks then available. Turnpike trusts were set up by individual Acts of Parliament, with powers to collect road tolls to repay loans for building, improving, and maintaining the principal roads in Britain. At their peak, in the 1830s, over 1,000 trusts[5] administered around 30,000 miles (48,000 km) of turnpike road in England and Wales, taking tolls at almost 8,000 toll-gates.[6] The trusts were ultimately responsible for the maintenance and improvement of most of the main roads in England and Wales, which were used to distribute agricultural and industrial goods economically. The tolls were a source of revenue for road building and maintenance, paid for by road users and not from general taxation. The turnpike trusts were gradually abolished from the 1870s. Most trusts improved existing roads, but some new roads, usually only short stretches, were also built. Thomas Telford's Holyhead road followed Watling Street from London but was exceptional in creating a largely new route beyond Shrewsbury, and especially beyond Llangollen. Built in the early 19th century, with many toll booths along its length, most of it is now the A5. In the modern day, one major toll road is the M6 Toll, relieving traffic congestion on the M6 in Birmingham. A few notable bridges and tunnels continue as toll roads including the Severn Bridge, the Dartford Crossing and Mersey Gateway bridge.

Some cities in Canada had toll roads in the 19th century. Roads radiating from Toronto required users to pay at toll gates along the street (Yonge Street, Bloor Street, Davenport Road, Kingston Road)[7] and disappeared after 1895.[8]

19th-century plank roads were usually operated as toll roads. One of the first U.S. motor roads, the Long Island Motor Parkway (which opened on October 10, 1908) was built by William Kissam Vanderbilt II, the great-grandson of Cornelius Vanderbilt. The road was closed in 1938 when it was taken over by the state of New York in lieu of back taxes.[9][10]

Main article: Road pricing

Road tolls were levied traditionally for a specific access (e.g. city) or for a specific infrastructure (e.g. roads, bridges). These concepts were widely used until the last century. However, the evolution in technology made it possible to implement road tolling policies based on different concepts. The different charging concepts are designed to suit different requirements regarding purpose of the charge, charging policy, the network to the charge, tariff class differentiation etc.:[11]

Time Based Charges and Access Fees: In a time-based charging regime, a road user has to pay for a given period of time in which they may use the associated infrastructure. For the practically identical access fees, the user pays for the access to a restricted zone for a period or several days.

Motorway and other Infrastructure Tolling: The term tolling is used for charging a well-defined special and comparatively costly infrastructure, like a bridge, a tunnel, a mountain pass, a motorway concession or the whole motorway network of a country. Classically a toll is due when a vehicle passes a tolling station, be it a manual barrier-controlled toll plaza or a free-flow multi-lane station.

Distance or Area Charging: In a distance or area charging system concept, vehicles are charged per total distance driven in a defined area.

Some toll roads charge a toll in only one direction. Examples include the Sydney Harbour Bridge, Sydney Harbour Tunnel and Eastern Distributor (these all charge tolls city-bound) in Australia, the Severn Bridges where the M4 and M48 in Great Britain crosses the River Severn, in the United States, crossings between Pennsylvania and New Jersey operated by Delaware River Port Authority and crossings between New Jersey and New York operated by Port Authority of New York and New Jersey.This technique is practical where the detour to avoid the toll is large or the toll differences are small.

.

Balintawak toll plaza of the North Luzon Expressway in Caloocan, Philippines. The toll barrier has both electronic toll collection and cash payment in the same barrier, before a new toll plaza was added. Tipo toll plaza in Subic–Clark–Tarlac Expressway, Hermosa, Bataan The open road tolling lanes at the West 163rd Street toll plaza, on the Tri-State Tollway near Markham, Illinois, United States

.

Overhead cameras and reader attach to gantry on Highway 407 in Ontario. See also: Electronic toll collection

Traditionally tolls were paid by hand at a toll gate. Although payments may still be made in cash, it is more common now to pay by credit card, by pre-paid card,[citation needed] or by an electronic toll collection system. In some places, payment is made using stickers which are affixed to the windscreen.

Three systems of toll roads exist: open (with mainline barrier toll plazas); closed (with entry/exit tolls) and open road (no toll booths, only electronic toll collection gantries at entrances and exits, or at strategic locations on the mainline of the road). Modern toll roads often use a combination of the three, with various entry and exit tolls supplemented by occasional mainline tolls: for example the Pennsylvania Turnpike and the New York State Thruway implement both systems in different sections.

On an open toll system, all vehicles stop at various locations along the highway to pay a toll. (Not to be confused with "open road tolling", where no vehicles stop to pay toll.) While this may save money from the lack of need to construct toll booths at every exit, it can cause traffic congestion while traffic queues at the mainline toll plazas (toll barriers). It is also possible for motorists to enter an 'open toll road' after one toll barrier and exit before the next one, thus travelling on the toll road toll-free. Most open toll roads have ramp tolls or partial access junctions to prevent this practice, known in the U.S. as "shunpiking".

With a closed system, vehicles collect a ticket when entering the highway. In some cases, the ticket displays the toll to be paid on exit. Upon exit, the driver must pay the amount listed for the given exit. Should the ticket be lost, a driver must typically pay the maximum amount possible for travel on that highway. Short toll roads with no intermediate entries or exits may have only one toll plaza at one end, with motorists traveling in either direction paying a flat fee either when they enter or when they exit the toll road. In a variant of the closed toll system, mainline barriers are present at the two endpoints of the toll road, and each interchange has a ramp toll that is paid upon exit or entry. In this case, a motorist pays a flat fee at the ramp toll and another flat fee at the end of the toll road; no ticket is necessary. In addition, with most systems, motorists may pay tolls only with cash and/or change; debit and credit cards are not accepted. However, some toll roads may have travel plazas with ATMs so motorists can stop and withdraw cash for the tolls.

The toll is calculated by the distance travelled on the toll road or the specific exit chosen. In the United States, for instance, the Kansas Turnpike, Ohio Turnpike, Pennsylvania Turnpike, New Jersey Turnpike, most of the Indiana Toll Road, New York State Thruway, and Florida's Turnpike currently implement closed systems.

The Union Toll Plaza on the Garden State Parkway was the first ever to use an automated toll collection machine. A plaque commemorating the event includes the first quarter collected at its toll booths.[12]

The first major deployment of an RFID electronic toll collection system in the United States was on the Dallas North Tollway in 1989 by Amtech (see TollTag). The Amtech RFID technology used on the Dallas North Tollway was originally developed at Sandia Labs for use in tagging and tracking livestock. In the same year, the Telepass active transponder RFID system was introduced across Italy.

Highway 407 in the province of Ontario, Canada, has no toll booths, and instead reads a transponder mounted on the windshields of each vehicle using the road (the rear licence plates of vehicles lacking a transponder are photographed when they enter and exit the highway). This made the highway the first all-automated toll highway in the world. A bill is mailed monthly for usage of the 407. Lower charges are levied on frequent 407 users who carry electronic transponders in their vehicles. The approach has not been without controversy: In 2003 the 407 ETR settled[13] a class action with a refund to users.

Throughout most of the East Coast of the United States, E-ZPass (operated under the brand I-Pass in Illinois) is accepted on almost all toll roads. Similar systems include SunPass in Florida, FasTrak in California, Good to Go in Washington State, and ExpressToll in Colorado. The systems use a small radio transponder mounted in or on a customer's vehicle to deduct toll fares from a pre-paid account as the vehicle passes through the toll barrier. This reduces manpower at toll booths and increases traffic flow and fuel efficiency by reducing the need for complete stops to pay tolls at these locations.

E-ZPass lanes at a New Jersey Turnpike (I-95) Toll Gate for Exit 8A in Monroe Township, New Jersey, United States

By designing a tollgate specifically for electronic collection, it is possible to carry out open-road tolling, where the customer does not need to slow at all when passing through the tollgate. The U.S. state of Texas is testing a system on a stretch of Texas 121 that has no toll booths. Drivers without a TollTag have their license plate photographed automatically and the registered owner will receive a monthly bill, at a higher rate than those vehicles with TollTags.[14]

The first all-electric toll road in the eastern United States, the InterCounty Connector (Maryland Route 200) was partially opened to traffic in February 2011,[15] and the final segment was completed in November 2014.[16] The first section of another all-electronic toll road, the Triangle Expressway, opened at the beginning of 2012 in North Carolina.[17]

Some toll roads are managed under such systems as the Build-Operate-Transfer (BOT) system. Private companies build the roads and are given a limited franchise. Ownership is transferred to the government when the franchise expires. This type of arrangement is prevalent in Australia, Canada, Hong Kong, India, South Korea, Japan and the Philippines. The BOT system is a fairly new concept that is gaining ground in the United States, with California, Delaware, Florida, Illinois, Indiana, Mississippi,[18] Texas, and Virginia already building and operating toll roads under this scheme. Pennsylvania, Massachusetts, New Jersey, and Tennessee are also considering the BOT methodology for future highway projects.

The more traditional means of managing toll roads in the United States is through semi-autonomous public authorities. Kansas, Maryland, Massachusetts, New Hampshire, New Jersey, New York, North Carolina, Ohio, Oklahoma, Pennsylvania, and West Virginia manage their toll roads in this manner. While most of the toll roads in California, Delaware, Florida, Texas, and Virginia are operating under the BOT arrangement, a few of the older toll roads in these states are still operated by public authorities.

In France, all toll roads are operated by private companies, and the government takes a part of their profit.[citation needed]

Toll roads have been criticized as being inefficient in various ways:[19]

  1. They require vehicles to stop or slow down (except open road tolling); manual toll collection wastes time and raises vehicle operating costs.
  2. Collection costs can absorb up to one-third of revenues, and revenue theft is considered to be comparatively easy.
  3. Where the tolled roads are less congested than the parallel "free" roads, the traffic diversion resulting from the tolls increases congestion on the road system and reduces its usefulness.
  4. By tracking the vehicle locations, their drivers are subject to an effectual restriction of their freedom of movement and freedom from excessive surveillance.

A number of additional criticisms are also directed at toll roads in general:

  1. Toll roads are a form of regressive taxation; that is, compared to conventional taxes for funding roads, they benefit wealthier citizens more than poor citizens.[20][21]
  2. If toll roads are owned or managed by private entities, the citizens may lose money overall compared to conventional public funding because the private owners/operators of the toll system will naturally seek to profit from the roads.[22]
  3. The managing entities, whether public or private, may not correctly account for the overall social costs, particularly to the poor, when setting pricing and thus may hurt the neediest segments of society.[23]
The Paving Company Costs

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