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For other uses, see Asphalt (disambiguation). Note: The terms bitumen and asphalt are mostly interchangeable, Asphalt Paving Cost in Duxberry except where asphalt is used as a shorthand for asphalt concrete. Natural bitumen from the Dead Sea Refined asphalt The University of Queensland pitch drop experiment, demonstrating the viscosity of asphalt

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Asphalt (/ˈæsˌfɔːlt, -ˌfɑːlt/), also known as bitumen (UK English: /ˈbɪtʃəmən, ˈbɪtjʊmən/,[1] US English: /bɪˈt(j)uːmən, baɪˈt(j)uːmən/)[2] is a sticky, black, and highly viscous liquid or semi-solid form of petroleum. It may be found in natural deposits or may be a refined product, and is classed as a pitch. Before the 20th century, the term asphaltum was also used.

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The primary use (70%) of asphalt Asphalt Driveway Resurfacing Companies is in road construction, where it is used as the glue or binder mixed with aggregate particles to create asphalt concrete. Its other main uses are for bituminous waterproofing products, including production of roofing felt and for sealing flat roofs.

The terms “asphalt” and “bitumen” are often used interchangeably to mean both natural and manufactured forms of the substance. In American English, “asphalt” (or “asphalt cement”) is commonly used for a refined residue from the distillation process of selected crude oils. Outside the United States, the product is often called “bitumen”, and geologists worldwide often prefer the term for the naturally occurring variety. Common colloquial usage often refers to various forms of asphalt as “tar”, as in the name of the La Brea Tar Pits.

Michigan left

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Naturally occurring asphalt is sometimes specified by the term “crude bitumen”. Asphalt Paving Cost Its viscosity is similar to that of cold molasses[6][7] while the material obtained from the fractional distillation of crude oil boiling at 525 °C (977 °F) is sometimes referred to as “refined bitumen”. The Canadian province of Alberta has most of the world’s reserves of natural asphalt in the Athabasca oil sands, which cover 142,000 square kilometres (55,000 sq mi), an area larger than England.

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The word “asphalt” is derived from the late Middle English, in turn from French asphalte, based on Late Latin asphalton, asphaltum, which is the latinisation of the Greek ἄσφαλτος (ásphaltos, ásphalton), a word meaning “asphalt/bitumen/pitch” which perhaps derives from ἀ-, “without” and σφάλλω (sfallō), “make fall”.  List Of Asphalt Companies the first use of asphalt by the ancients was in the nature of a cement for securing or joining together various objects, and it thus seems likely that the name itself was expressive of this application. Specifically, Herodotus mentioned that bitumen was brought to Babylon to build its gigantic fortification wall.[11] From the Greek, the word passed into late Latin, and thence into French (asphalte) and English (“asphaltum” and “asphalt”). In French, the term asphalte is used for naturally occurring asphalt-soaked limestone deposits, and for specialised manufactured products with fewer voids or greater bitumen content than the “asphaltic concrete” used to pave roads.

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The expression “bitumen” originated in the Sanskrit words jatu, meaning “pitch”, and jatu-krit, meaning “pitch creating” or “pitch producing” (referring to coniferous or resinous trees). The Latin equivalent is claimed by some to be originally gwitu-men (pertaining to pitch), and by others, pixtumens (exuding or bubbling pitch), which was subsequently shortened to bitumen, thence passing via French into English. From the same root is derived the Anglo-Saxon word cwidu (mastix), the German word Kitt (cement or mastic) and the old Norse word kvada.

In British English, “bitumen” is used instead of “asphalt”. The word “asphalt” is instead used to refer to asphalt concrete, a mixture of construction aggregate and asphalt itself (also called “tarmac” in common parlance). Bitumen mixed with clay was usually called “asphaltum”,[13] but the term is less commonly used today.[citation needed]

Brick

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In Australian English, “bitumen” is often used as the generic term for road surfaces.

In American English, “asphalt” is equivalent to the British “bitumen”. However, “asphalt” is also commonly used as a shortened form of “asphalt concrete” (therefore equivalent to the British “asphalt” or “tarmac”).

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In Canadian English, the word “bitumen” is used to refer to the vast Canadian deposits of extremely heavy crude oil,[14] while “asphalt” is used for the oil refinery product. Diluted bitumen (diluted with naphtha to make it flow in pipelines) is known as “dilbit” in the Canadian petroleum industry, while bitumen “upgraded” to synthetic crude oil is known as “syncrude”, and syncrude blended with bitumen is called “synbit”.[15]

“Bitumen” is still the preferred geological term for naturally occurring deposits of the solid or semi-solid form of petroleum. “Bituminous rock” is a form of sandstone impregnated with bitumen. The tar sands of Alberta, Canada are a similar material.

Asphalt Paving Cost Estimate

Neither of the terms “asphalt” or “bitumen” should be confused with tar or coal tars.[further explanation needed]

See also: Asphaltene

The components of asphalt include four main classes of compounds:

The naphthene aromatics and polar aromatics are typically the majority components. Most natural bitumens also contain organosulfur compounds, resulting in an overall sulfur content of up to 4%. Nickel and vanadium are found at <10 parts per million, as is typical of some petroleum.

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The substance is soluble in carbon disulfide. It is commonly modelled as a colloid, with asphaltenes as the dispersed phase and maltenes as the continuous phase.[16] “It is almost impossible to separate and identify all the different molecules of asphalt, because the number of molecules with different chemical structure is extremely large”.

Asphalt may be confused with coal tar, which is a visually similar black, thermoplastic material produced by the destructive distillation of coal. During the early and mid-20th century, when town gas was produced, coal tar was a readily available byproduct and extensively used as the binder for road aggregates. The addition of coal tar to macadam roads led to the word “tarmac”, which is now used in common parlance to refer to road-making materials. However, since the 1970s, when natural gas succeeded town gas, asphalt has completely overtaken the use of coal tar in these applications. Other examples of this confusion include the La Brea Tar Pits and the Canadian oil sands, both of which actually contain natural bitumen rather than tar. “Pitch” is another term sometimes informally used at times to refer to asphalt, as in Pitch Lake.

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Bituminous outcrop of the Puy de la Poix, Clermont-Ferrand, France

The majority of asphalt used commercially is obtained from petroleum.[18] Nonetheless, large amounts of asphalt occur in concentrated form in nature. Naturally occurring deposits of bitumen are formed from the remains of ancient, microscopic algae (diatoms) and other once-living things. These remains were deposited in the mud on the bottom of the ocean or lake where the organisms lived. Under the heat (above 50 °C) and pressure of burial deep in the earth, the remains were transformed into materials such as bitumen, kerogen, or petroleum.

Natural deposits of bitumen include lakes such as the Pitch Lake in Trinidad and Tobago and Lake Bermudez in Venezuela. Natural seeps occur in the La Brea Tar Pits and in the Dead Sea.

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Bitumen also occurs in unconsolidated sandstones known as “oil sands” in Alberta, Canada, and the similar “tar sands” in Utah, US. The Canadian province of Alberta has most of the world’s reserves, in three huge deposits covering 142,000 square kilometres (55,000 sq mi), an area larger than England or New York state. These bituminous sands contain 166 billion barrels (26.4×10^9 m3) of commercially established oil reserves, giving Canada the third largest oil reserves in the world. Although historically it was used without refining to pave roads, nearly all of the output is now used as raw material for oil refineries in Canada and the United States.

Sidewalk

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The world’s largest deposit of natural bitumen, known as the Athabasca oil sands, is located in the McMurray Formation of Northern Alberta. This formation is from the early Cretaceous, and is composed of numerous lenses of oil-bearing sand with up to 20% oil.[19] Isotopic studies show the oil deposits to be about 110 million years old.[20] Two smaller but still very large formations occur in the Peace River oil sands and the Cold Lake oil sands, to the west and southeast of the Athabasca oil sands, respectively. Of the Alberta deposits, only parts of the Athabasca oil sands are shallow enough to be suitable for surface mining. The other 80% has to be produced by oil wells using enhanced oil recovery techniques like steam-assisted gravity drainage.

Asphalt Driveway Paving Price

Much smaller heavy oil or bitumen deposits also occur in the Uinta Basin in Utah, US. The Tar Sand Triangle deposit, for example, is roughly 6% bitumen.

Bitumen may occur in hydrothermal veins. An example of this is within the Uinta Basin of Utah, in the US, where there is a swarm of laterally and vertically extensive veins composed of a solid hydrocarbon termed Gilsonite. These veins formed by the polymerization and solidification of hydrocarbons that were mobilized from the deeper oil shales of the Green River Formation during burial and diagenesis.

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Bitumen is similar to the organic matter in carbonaceous meteorites.[23] However, detailed studies have shown these materials to be distinct.[24] The vast Alberta bitumen resources are considered to have started out as living material from marine plants and animals, mainly algae, that died millions of years ago when an ancient ocean covered Alberta. They were covered by mud, buried deeply over time, and gently cooked into oil by geothermal heat at a temperature of 50 to 150 °C (120 to 300 °F). Due to pressure from the rising of the Rocky Mountains in southwestern Alberta, 80 to 55 million years ago, the oil was driven northeast hundreds of kilometres and trapped into underground sand deposits left behind by ancient river beds and ocean beaches, thus forming the oil sands.

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The use of natural bitumen for waterproofing, and as an adhesive dates at least to the fifth millennium BC, with a crop storage basket discovered in Mehrgarh, of the Indus Valley Civilization, lined with it.[25] By the 3rd millennia BC refined rock asphalt was in use, in the region, and was used to waterproof the Great Bath, Mohenjo-daro.

In the ancient Middle East, the Sumerians used natural bitumen deposits for mortar between bricks and stones, to cement parts of carvings, such as eyes, into place, for ship caulking, and for waterproofing.[3] The Greek historian Herodotus said hot bitumen was used as mortar in the walls of Babylon.

Residential Paving Cost Estimate

The 1 kilometre (0.62 mi) long Euphrates Tunnel beneath the river Euphrates at Babylon in the time of Queen Semiramis (ca. 800 BC) was reportedly constructed of burnt bricks covered with bitumen as a waterproofing agent.

Bitumen was used by ancient Egyptians to embalm mummies.[3][28] The Persian word for asphalt is moom, which is related to the English word mummy. The Egyptians’ primary source of bitumen was the Dead Sea, which the Romans knew as Palus Asphaltites (Asphalt Lake).

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Approximately 40 AD, Dioscorides described the Dead Sea material as Judaicum bitumen, and noted other places in the region where it could be found.[29] The Sidon bitumen is thought to refer to material found at Hasbeya.[30] Pliny refers also to bitumen being found in Epirus. It was a valuable strategic resource, the object of the first known battle for a hydrocarbon deposit—between the Seleucids and the Nabateans in 312 BC.

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In the ancient Far East, natural bitumen was slowly boiled to get rid of the higher fractions, leaving a thermoplastic material of higher molecular weight that when layered on objects became quite hard upon cooling. This was used to cover objects that needed waterproofing,[3] such as scabbards and other items. Statuettes of household deities were also cast with this type of material in Japan, and probably also in China.

In North America, archaeological recovery has indicated bitumen was sometimes used to adhere stone projectile points to wooden shafts.[32] In Canada, aboriginal people used bitumen seeping out of the banks of the Athabasca and other rivers to waterproof birch bark canoes, and also heated it in smudge pots to ward off mosquitoes in the summer.

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In 1553, Pierre Belon described in his work Observations that pissasphalto, a mixture of pitch and bitumen, was used in the Republic of Ragusa (now Dubrovnik, Croatia) for tarring of ships.

Crocodile cracking

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An 1838 edition of Mechanics Magazine cites an early use of asphalt in France. A pamphlet dated 1621, by “a certain Monsieur d’Eyrinys, states that he had discovered the existence (of asphaltum) in large quantities in the vicinity of Neufchatel”, and that he proposed to use it in a variety of ways – “principally in the construction of air-proof granaries, and in protecting, by means of the arches, the water-courses in the city of Paris from the intrusion of dirt and filth”, which at that time made the water unusable. “He expatiates also on the excellence of this material for forming level and durable terraces” in palaces, “the notion of forming such terraces in the streets not one likely to cross the brain of a Parisian of that generation”.

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But the substance was generally neglected in France until the revolution of 1830. In the 1830s there was a surge of interest, and asphalt became widely used “for pavements, flat roofs, and the lining of cisterns, and in England, some use of it had been made of it for similar purposes”. Its rise in Europe was “a sudden phenomenon”, after natural deposits were found “in France at Osbann (Bas-Rhin), the Parc (Ain) and the Puy-de-la-Poix (Puy-de-Dôme)”, although it could also be made artificially.[35] One of the earliest uses in France was the laying of about 24,000 square yards of Seyssel asphalt at the Place de la Concorde in 1835.

Among the earlier uses of bitumen in the United Kingdom was for etching. William Salmon’s Polygraphice (1673) provides a recipe for varnish used in etching, consisting of three ounces of virgin wax, two ounces of mastic, and one ounce of asphaltum.[37] By the fifth edition in 1685, he had included more asphaltum recipes from other sources.

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The first British patent for the use of asphalt was “Cassell’s patent asphalte or bitumen” in 1834.[35] Then on 25 November 1837, Richard Tappin Claridge patented the use of Seyssel asphalt (patent #7849), for use in asphalte pavement,[39][40] having seen it employed in France and Belgium when visiting with Frederick Walter Simms, who worked with him on the introduction of asphalt to Britain.[41][42] Dr T. Lamb Phipson writes that his father, Samuel Ryland Phipson, a friend of Claridge, was also “instrumental in introducing the asphalte pavement (in 1836)”.[43] Indeed, mastic pavements had been previously employed at Vauxhall by a competitor of Claridge, but without success.

Sealcoat

Asphalt Driveway Paving Price

Claridge obtained a patent in Scotland on 27 March 1838, and obtained a patent in Ireland on 23 April 1838. In 1851, extensions for the 1837 patent and for both 1838 patents were sought by the trustees of a company previously formed by Claridge. Claridge’s Patent Asphalte Company—formed in 1838 for the purpose of introducing to Britain “Asphalte in its natural state from the mine at Pyrimont Seysell in France”,—”laid one of the first asphalt pavements in Whitehall”.  Trials were made of the pavement in 1838 on the footway in Whitehall, the stable at Knightsbridge Barracks,”and subsequently on the space at the bottom of the steps leading from Waterloo Place to St. James Park”. “The formation in 1838 of Claridge’s Patent Asphalte Company (with a distinguished list of aristocratic patrons, and Marc and Isambard Brunel as, respectively, a trustee and consulting engineer), gave an enormous impetus to the development of a British asphalt industry”.[45] “By the end of 1838, at least two other companies, Robinson’s and the Bastenne company, were in production”,[50] with asphalt being laid as paving at Brighton, Herne Bay, Canterbury, Kensington, the Strand, and a large floor area in Bunhill-row, while meantime Claridge’s Whitehall paving “continue(d) in good order”.

Asphalt Paving Cost in Duxberry ?

Driveway Pavers Cost Estimate For other uses, see Asphalt (disambiguation). Note: The terms bitumen and asphalt are mostly interchangeable, except where asphalt is used as a shorthand for asphalt concrete. Natural bitumen from the Dead Sea Refined asphalt The University of Queensland pitch drop experiment, demonstrating the viscosity of asphalt

Asphalt (/ˈæsˌfɔːlt, -ˌfɑːlt/), also known as bitumen (UK English: /ˈbɪəmən, ˈbɪtjʊmən/,[1] US English: /bɪˈt(j)mən, bˈt(j)mən/)[2] is a sticky, black, and highly viscous liquid or semi-solid form of petroleum. It may be found in natural deposits or may be a refined product, and is classed as a pitch. Before the 20th century, the term asphaltum was also used.[3] The word is derived from the Ancient Greek ἄσφαλτος ásphaltos.[4]

The primary use (70%) of asphalt is in road construction, where it is used as the glue or binder mixed with aggregate particles to create asphalt concrete. Its other main uses are for bituminous waterproofing products, including production of roofing felt and for sealing flat roofs.[5]

The terms "asphalt" and "bitumen" are often used interchangeably to mean both natural and manufactured forms of the substance. In American English, "asphalt" (or "asphalt cement") is commonly used for a refined residue from the distillation process of selected crude oils. Outside the United States, the product is often called "bitumen", and geologists worldwide often prefer the term for the naturally occurring variety. Common colloquial usage often refers to various forms of asphalt as "tar", as in the name of the La Brea Tar Pits.

Naturally occurring asphalt is sometimes specified by the term "crude bitumen". Its viscosity is similar to that of cold molasses[6][7] while the material obtained from the fractional distillation of crude oil boiling at 525 °C (977 °F) is sometimes referred to as "refined bitumen". The Canadian province of Alberta has most of the world's reserves of natural asphalt in the Athabasca oil sands, which cover 142,000 square kilometres (55,000 sq mi), an area larger than England.[8]

The word "asphalt" is derived from the late Middle English, in turn from French asphalte, based on Late Latin asphalton, asphaltum, which is the latinisation of the Greek ἄσφαλτος (ásphaltos, ásphalton), a word meaning "asphalt/bitumen/pitch",[9] which perhaps derives from ἀ-, "without" and σφάλλω (sfallō), "make fall".[10] The first use of asphalt by the ancients was in the nature of a cement for securing or joining together various objects, and it thus seems likely that the name itself was expressive of this application. Specifically, Herodotus mentioned that bitumen was brought to Babylon to build its gigantic fortification wall.[11] From the Greek, the word passed into late Latin, and thence into French (asphalte) and English ("asphaltum" and "asphalt"). In French, the term asphalte is used for naturally occurring asphalt-soaked limestone deposits, and for specialised manufactured products with fewer voids or greater bitumen content than the "asphaltic concrete" used to pave roads.

The expression "bitumen" originated in the Sanskrit words jatu, meaning "pitch", and jatu-krit, meaning "pitch creating" or "pitch producing" (referring to coniferous or resinous trees). The Latin equivalent is claimed by some to be originally gwitu-men (pertaining to pitch), and by others, pixtumens (exuding or bubbling pitch), which was subsequently shortened to bitumen, thence passing via French into English. From the same root is derived the Anglo-Saxon word cwidu (mastix), the German word Kitt (cement or mastic) and the old Norse word kvada.[12]

In British English, "bitumen" is used instead of "asphalt". The word "asphalt" is instead used to refer to asphalt concrete, a mixture of construction aggregate and asphalt itself (also called "tarmac" in common parlance). Bitumen mixed with clay was usually called "asphaltum",[13] but the term is less commonly used today.[citation needed]

In Australian English, "bitumen" is often used as the generic term for road surfaces.

In American English, "asphalt" is equivalent to the British "bitumen". However, "asphalt" is also commonly used as a shortened form of "asphalt concrete" (therefore equivalent to the British "asphalt" or "tarmac").

In Canadian English, the word "bitumen" is used to refer to the vast Canadian deposits of extremely heavy crude oil,[14] while "asphalt" is used for the oil refinery product. Diluted bitumen (diluted with naphtha to make it flow in pipelines) is known as "dilbit" in the Canadian petroleum industry, while bitumen "upgraded" to synthetic crude oil is known as "syncrude", and syncrude blended with bitumen is called "synbit".[15]

"Bitumen" is still the preferred geological term for naturally occurring deposits of the solid or semi-solid form of petroleum. "Bituminous rock" is a form of sandstone impregnated with bitumen. The tar sands of Alberta, Canada are a similar material.

Neither of the terms "asphalt" or "bitumen" should be confused with tar or coal tars.[further explanation needed]

See also: Asphaltene

The components of asphalt include four main classes of compounds:

The naphthene aromatics and polar aromatics are typically the majority components. Most natural bitumens also contain organosulfur compounds, resulting in an overall sulfur content of up to 4%. Nickel and vanadium are found at <10 parts per million, as is typical of some petroleum.[5]

The substance is soluble in carbon disulfide. It is commonly modelled as a colloid, with asphaltenes as the dispersed phase and maltenes as the continuous phase.[16] "It is almost impossible to separate and identify all the different molecules of asphalt, because the number of molecules with different chemical structure is extremely large".[17]

Asphalt may be confused with coal tar, which is a visually similar black, thermoplastic material produced by the destructive distillation of coal. During the early and mid-20th century, when town gas was produced, coal tar was a readily available byproduct and extensively used as the binder for road aggregates. The addition of coal tar to macadam roads led to the word "tarmac", which is now used in common parlance to refer to road-making materials. However, since the 1970s, when natural gas succeeded town gas, asphalt has completely overtaken the use of coal tar in these applications. Other examples of this confusion include the La Brea Tar Pits and the Canadian oil sands, both of which actually contain natural bitumen rather than tar. "Pitch" is another term sometimes informally used at times to refer to asphalt, as in Pitch Lake.

Bituminous outcrop of the Puy de la Poix, Clermont-Ferrand, France

The majority of asphalt used commercially is obtained from petroleum.[18] Nonetheless, large amounts of asphalt occur in concentrated form in nature. Naturally occurring deposits of bitumen are formed from the remains of ancient, microscopic algae (diatoms) and other once-living things. These remains were deposited in the mud on the bottom of the ocean or lake where the organisms lived. Under the heat (above 50 °C) and pressure of burial deep in the earth, the remains were transformed into materials such as bitumen, kerogen, or petroleum.

Natural deposits of bitumen include lakes such as the Pitch Lake in Trinidad and Tobago and Lake Bermudez in Venezuela. Natural seeps occur in the La Brea Tar Pits and in the Dead Sea.

Bitumen also occurs in unconsolidated sandstones known as "oil sands" in Alberta, Canada, and the similar "tar sands" in Utah, US. The Canadian province of Alberta has most of the world's reserves, in three huge deposits covering 142,000 square kilometres (55,000 sq mi), an area larger than England or New York state. These bituminous sands contain 166 billion barrels (26.4×10^9 m3) of commercially established oil reserves, giving Canada the third largest oil reserves in the world. Although historically it was used without refining to pave roads, nearly all of the output is now used as raw material for oil refineries in Canada and the United States.[8]

The world's largest deposit of natural bitumen, known as the Athabasca oil sands, is located in the McMurray Formation of Northern Alberta. This formation is from the early Cretaceous, and is composed of numerous lenses of oil-bearing sand with up to 20% oil.[19] Isotopic studies show the oil deposits to be about 110 million years old.[20] Two smaller but still very large formations occur in the Peace River oil sands and the Cold Lake oil sands, to the west and southeast of the Athabasca oil sands, respectively. Of the Alberta deposits, only parts of the Athabasca oil sands are shallow enough to be suitable for surface mining. The other 80% has to be produced by oil wells using enhanced oil recovery techniques like steam-assisted gravity drainage.[21]

Much smaller heavy oil or bitumen deposits also occur in the Uinta Basin in Utah, US. The Tar Sand Triangle deposit, for example, is roughly 6% bitumen.[19]

Bitumen may occur in hydrothermal veins. An example of this is within the Uinta Basin of Utah, in the US, where there is a swarm of laterally and vertically extensive veins composed of a solid hydrocarbon termed Gilsonite. These veins formed by the polymerization and solidification of hydrocarbons that were mobilized from the deeper oil shales of the Green River Formation during burial and diagenesis.[22]

Bitumen is similar to the organic matter in carbonaceous meteorites.[23] However, detailed studies have shown these materials to be distinct.[24] The vast Alberta bitumen resources are considered to have started out as living material from marine plants and animals, mainly algae, that died millions of years ago when an ancient ocean covered Alberta. They were covered by mud, buried deeply over time, and gently cooked into oil by geothermal heat at a temperature of 50 to 150 °C (120 to 300 °F). Due to pressure from the rising of the Rocky Mountains in southwestern Alberta, 80 to 55 million years ago, the oil was driven northeast hundreds of kilometres and trapped into underground sand deposits left behind by ancient river beds and ocean beaches, thus forming the oil sands.[21]

The use of natural bitumen for waterproofing, and as an adhesive dates at least to the fifth millennium BC, with a crop storage basket discovered in Mehrgarh, of the Indus Valley Civilization, lined with it.[25] By the 3rd millennia BC refined rock asphalt was in use, in the region, and was used to waterproof the Great Bath, Mohenjo-daro.

In the ancient Middle East, the Sumerians used natural bitumen deposits for mortar between bricks and stones, to cement parts of carvings, such as eyes, into place, for ship caulking, and for waterproofing.[3] The Greek historian Herodotus said hot bitumen was used as mortar in the walls of Babylon.[26]

The 1 kilometre (0.62 mi) long Euphrates Tunnel beneath the river Euphrates at Babylon in the time of Queen Semiramis (ca. 800 BC) was reportedly constructed of burnt bricks covered with bitumen as a waterproofing agent.[27]

Bitumen was used by ancient Egyptians to embalm mummies.[3][28] The Persian word for asphalt is moom, which is related to the English word mummy. The Egyptians' primary source of bitumen was the Dead Sea, which the Romans knew as Palus Asphaltites (Asphalt Lake).

Approximately 40 AD, Dioscorides described the Dead Sea material as Judaicum bitumen, and noted other places in the region where it could be found.[29] The Sidon bitumen is thought to refer to material found at Hasbeya.[30] Pliny refers also to bitumen being found in Epirus. It was a valuable strategic resource, the object of the first known battle for a hydrocarbon deposit—between the Seleucids and the Nabateans in 312 BC.[31]

In the ancient Far East, natural bitumen was slowly boiled to get rid of the higher fractions, leaving a thermoplastic material of higher molecular weight that when layered on objects became quite hard upon cooling. This was used to cover objects that needed waterproofing,[3] such as scabbards and other items. Statuettes of household deities were also cast with this type of material in Japan, and probably also in China.

In North America, archaeological recovery has indicated bitumen was sometimes used to adhere stone projectile points to wooden shafts.[32] In Canada, aboriginal people used bitumen seeping out of the banks of the Athabasca and other rivers to waterproof birch bark canoes, and also heated it in smudge pots to ward off mosquitoes in the summer.[21]

In 1553, Pierre Belon described in his work Observations that pissasphalto, a mixture of pitch and bitumen, was used in the Republic of Ragusa (now Dubrovnik, Croatia) for tarring of ships.[33]

An 1838 edition of Mechanics Magazine cites an early use of asphalt in France. A pamphlet dated 1621, by "a certain Monsieur d'Eyrinys, states that he had discovered the existence (of asphaltum) in large quantities in the vicinity of Neufchatel", and that he proposed to use it in a variety of ways – "principally in the construction of air-proof granaries, and in protecting, by means of the arches, the water-courses in the city of Paris from the intrusion of dirt and filth", which at that time made the water unusable. "He expatiates also on the excellence of this material for forming level and durable terraces" in palaces, "the notion of forming such terraces in the streets not one likely to cross the brain of a Parisian of that generation".[34]

But the substance was generally neglected in France until the revolution of 1830. In the 1830s there was a surge of interest, and asphalt became widely used "for pavements, flat roofs, and the lining of cisterns, and in England, some use of it had been made of it for similar purposes". Its rise in Europe was "a sudden phenomenon", after natural deposits were found "in France at Osbann (Bas-Rhin), the Parc (Ain) and the Puy-de-la-Poix (Puy-de-Dôme)", although it could also be made artificially.[35] One of the earliest uses in France was the laying of about 24,000 square yards of Seyssel asphalt at the Place de la Concorde in 1835.[36]

Among the earlier uses of bitumen in the United Kingdom was for etching. William Salmon's Polygraphice (1673) provides a recipe for varnish used in etching, consisting of three ounces of virgin wax, two ounces of mastic, and one ounce of asphaltum.[37] By the fifth edition in 1685, he had included more asphaltum recipes from other sources.[38]

The first British patent for the use of asphalt was "Cassell's patent asphalte or bitumen" in 1834.[35] Then on 25 November 1837, Richard Tappin Claridge patented the use of Seyssel asphalt (patent #7849), for use in asphalte pavement,[39][40] having seen it employed in France and Belgium when visiting with Frederick Walter Simms, who worked with him on the introduction of asphalt to Britain.[41][42] Dr T. Lamb Phipson writes that his father, Samuel Ryland Phipson, a friend of Claridge, was also "instrumental in introducing the asphalte pavement (in 1836)".[43] Indeed, mastic pavements had been previously employed at Vauxhall by a competitor of Claridge, but without success.[36]

Claridge obtained a patent in Scotland on 27 March 1838, and obtained a patent in Ireland on 23 April 1838. In 1851, extensions for the 1837 patent and for both 1838 patents were sought by the trustees of a company previously formed by Claridge.[35][44][45][46] Claridge's Patent Asphalte Company—formed in 1838 for the purpose of introducing to Britain "Asphalte in its natural state from the mine at Pyrimont Seysell in France",[47]—"laid one of the first asphalt pavements in Whitehall".[48] Trials were made of the pavement in 1838 on the footway in Whitehall, the stable at Knightsbridge Barracks,[47][49] "and subsequently on the space at the bottom of the steps leading from Waterloo Place to St. James Park".[49] "The formation in 1838 of Claridge's Patent Asphalte Company (with a distinguished list of aristocratic patrons, and Marc and Isambard Brunel as, respectively, a trustee and consulting engineer), gave an enormous impetus to the development of a British asphalt industry".[45] "By the end of 1838, at least two other companies, Robinson's and the Bastenne company, were in production",[50] with asphalt being laid as paving at Brighton, Herne Bay, Canterbury, Kensington, the Strand, and a large floor area in Bunhill-row, while meantime Claridge's Whitehall paving "continue(d) in good order".[51]

In 1838, there was a flurry of entrepreneurial activity involving asphalt, which had uses beyond paving. For example, asphalt could also be used for flooring, damp proofing in buildings, and for waterproofing of various types of pools and baths, both of which were also proliferating in the 19th century.[3][35][52] On the London stockmarket, there were various claims as to the exclusivity of asphalt quality from France, Germany and England. And numerous patents were granted in France, with similar numbers of patent applications being denied in England due to their similarity to each other. In England, "Claridge's was the type most used in the 1840s and 50s".[50]

In 1914, Claridge's Company entered into a joint venture to produce tar-bound macadam,[53] with materials manufactured through a subsidiary company called Clarmac Roads Ltd.[54] Two products resulted, namely Clarmac, and Clarphalte, with the former being manufactured by Clarmac Roads and the latter by Claridge's Patent Asphalte Co., although Clarmac was more widely used.[55][note 1] However, the First World War ruined the Clarmac Company, which entered into liquidation in 1915.[57][58] The failure of Clarmac Roads Ltd had a flow-on effect to Claridge's Company, which was itself compulsorily wound up,[59] ceasing operations in 1917,[60][61] having invested a substantial amount of funds into the new venture, both at the outset[59] and in a subsequent attempt to save the Clarmac Company.[57]

The first use of bitumen in the New World was by indigenous peoples. On the west coast, as early as the 13th century, the Tongva, Luiseño and Chumash peoples collected the naturally occurring bitumen that seeped to the surface above underlying petroleum deposits. All three groups used the substance as an adhesive. It is found on many different artifacts of tools and ceremonial items. For example, it was used on rattles to adhere gourds or turtle shells to rattle handles. It was also used in decorations. Small round shell beads were often set in asphaltum to provide decorations. It was used as a sealant on baskets to make them watertight for carrying water, possibly poisoning those who drank the water.[62] Asphalt was used also to seal the planks on ocean-going canoes.

Asphalt was first used to pave streets in the 1870s. At first naturally occurring "bituminous rock" was used, such as at Ritchie Mines in Macfarlan in Ritchie County, West Virginia from 1852 to 1873. In 1876, asphalt-based paving was used to pave Pennsylvania Avenue in Washington DC, in time for the celebration of the national centennial.[63] In the horse-drawn era, streets were unpaved and covered with dirt or gravel. However, that produced uneven wear, opened new hazards for pedestrians and made for dangerous potholes for bicycles and for motor vehicles. Manhattan alone had 130,000 horses in 1900, pulling streetcars, wagons, and carriages, and leaving their waste behind. They were not fast, and pedestrians could dodge and scramble their way across the crowded streets. Small towns continued to rely on dirt and gravel, but larger cities wanted much better streets. They looked to wood or granite blocks by the 1850s.[64] In 1890, a third of Chicago's 2000 miles of streets were paved, chiefly with wooden blocks, which gave better traction than mud. Brick surfacing was a good compromise, but even better was asphalt paving, which was easy to install and to cut through to get at sewers. With London and Paris serving as models, Washington laid 400,000 square yards of asphalt paving by 1882; it became the model for Buffalo, Philadelphia and elsewhere. By the end of the century, American cities boasted 30 million square yards of asphalt paving, well ahead of brick.[65] The streets became faster and more dangerous so electric traffic lights were installed. Electric trolleys (at 12 miles per hour) became the main transportation service for middle class shoppers and office workers until they bought automobiles after 1945 and commuted from more distant suburbs in privacy and comfort on asphalt highways.[66]

See also: Bitumount and History of the petroleum industry in Canada (oil sands and heavy oil)

Canada has the world's largest deposit of natural bitumen in the Athabasca oil sands, and Canadian First Nations along the Athabasca River had long used it to waterproof their canoes. In 1719, a Cree named Wa-Pa-Su brought a sample for trade to Henry Kelsey of the Hudson’s Bay Company, who was the first recorded European to see it. However, it wasn't until 1787 that fur trader and explorer Alexander MacKenzie saw the Athabasca oil sands and said, "At about 24 miles from the fork (of the Athabasca and Clearwater Rivers) are some bituminous fountains into which a pole of 20 feet long may be inserted without the least resistance."[21]

The value of the deposit was obvious from the start, but the means of extracting the bitumen was not. The nearest town, Fort McMurray, Alberta, was a small fur trading post, other markets were far away, and transportation costs were too high to ship the raw bituminous sand for paving. In 1915, Sidney Ells of the Federal Mines Branch experimented with separation techniques and used the product to pave 600 feet of road in Edmonton, Alberta. Other roads in Alberta were paved with material extracted from oil sands, but it was generally not economic. During the 1920s Dr. Karl A. Clark of the Alberta Research Council patented a hot water oil separation process and entrepreneur Robert C. Fitzsimmons[67] built the Bitumount oil separation plant, which between 1925 and 1958 produced up to 300 barrels (50 m3) per day of bitumen using Dr. Clark's method. Most of the bitumen was used for waterproofing roofs, but other uses included fuels, lubrication oils, printers ink, medicines, rust- and acid-proof paints, fireproof roofing, street paving, patent leather, and fence post preservatives.[21] Eventually Fitzsimmons ran out of money and the plant was taken over by the Alberta government. Today the Bitumount plant is a Provincial Historic Site.[68]

Bitumen was used in early photographic technology. In 1826 or 1827, it was used by French scientist Joseph Nicéphore Niépce to make the oldest surviving photograph from nature. The bitumen was thinly coated onto a pewter plate which was then exposed in a camera. Exposure to light hardened the bitumen and made it insoluble, so that when it was subsequently rinsed with a solvent only the sufficiently light-struck areas remained. Many hours of exposure in the camera were required, making bitumen impractical for ordinary photography, but from the 1850s to the 1920s it was in common use as a photoresist in the production of printing plates for various photomechanical printing processes.[69][70]

Bitumen was the nemesis of many artists during the 19th century. Although widely used for a time, it ultimately proved unstable for use in oil painting, especially when mixed with the most common diluents, such as linseed oil, varnish and turpentine. Unless thoroughly diluted, bitumen never fully solidifies and will in time corrupt the other pigments with which it comes into contact. The use of bitumen as a glaze to set in shadow or mixed with other colors to render a darker tone resulted in the eventual deterioration of many paintings, for instance those of Delacroix. Perhaps the most famous example of the destructiveness of bitumen is Théodore Géricault's Raft of the Medusa (1818–1819), where his use of bitumen caused the brilliant colors to degenerate into dark greens and blacks and the paint and canvas to buckle.[71]

The vast majority of refined asphalt is used in construction: primarily as a constituent of products used in paving and roofing applications. According to the requirements of the end use, asphalt is produced to specification. This is achieved either by refining or blending. It is estimated that the current world use of asphalt is approximately 102 million tonnes per year. Approximately 85% of all the asphalt produced is used as the binder in asphalt concrete for roads. It is also used in other paved areas such as airport runways, car parks and footways. Typically, the production of asphalt concrete involves mixing fine and coarse aggregates such as sand, gravel and crushed rock with asphalt, which acts as the binding agent. Other materials, such as recycled polymers (e.g., rubber tyres), may be added to the asphalt to modify its properties according to the application for which the asphalt is ultimately intended.

A further 10% of global asphalt production is used in roofing applications, where its waterproofing qualities are invaluable. The remaining 5% of asphalt is used mainly for sealing and insulating purposes in a variety of building materials, such as pipe coatings, carpet tile backing and paint. Asphalt is applied in the construction and maintenance of many structures, systems, and components, such as the following:

Main article: Asphalt concrete

The largest use of asphalt is for making asphalt concrete for road surfaces; this accounts for approximately 85% of the asphalt consumed in the United States. Asphalt concrete pavement mixes are typically composed of 5% asphalt cement and 95% aggregates (stone, sand, and gravel). Due to its highly viscous nature, asphalt cement must be heated so it can be mixed with the aggregates at the asphalt mixing facility. The temperature required varies depending upon characteristics of the asphalt and the aggregates, but warm-mix asphalt technologies allow producers to reduce the temperature required. There are about 4,000 asphalt concrete mixing plants in the US, and a similar number in Europe.[72]

When maintenance is performed on asphalt pavements, such as milling to remove a worn or damaged surface, the removed material can be returned to a facility for processing into new pavement mixtures. The asphalt in the removed material can be reactivated and put back to use in new pavement mixes.[73] With some 95% of paved roads being constructed of or surfaced with asphalt,[74] a substantial amount of asphalt pavement material is reclaimed each year. According to industry surveys conducted annually by the Federal Highway Administration and the National Asphalt Pavement Association, more than 99% of the asphalt removed each year from road surfaces during widening and resurfacing projects is reused as part of new pavements, roadbeds, shoulders and embankments.[75]

Asphalt concrete paving is widely used in airports around the world. Due to the sturdiness and ability to be repaired quickly, it is widely used for runways.

Further information: Fibre mastic asphalt

Mastic asphalt is a type of asphalt that differs from dense graded asphalt (asphalt concrete) in that it has a higher asphalt (binder) content, usually around 7–10% of the whole aggregate mix, as opposed to rolled asphalt concrete, which has only around 5% asphalt. This thermoplastic substance is widely used in the building industry for waterproofing flat roofs and tanking underground. Mastic asphalt is heated to a temperature of 210 °C (410 °F) and is spread in layers to form an impervious barrier about 20 millimeters (0.8 inches) thick.

A number of technologies allow asphalt to be mixed at much lower temperatures. These involve mixing with petroleum solvents to form "cutbacks" with reduced melting point or mixing with water to turn the asphalt into an emulsion. Asphalt emulsions contain up to 70% asphalt and typically less than 1.5% chemical additives. There are two main types of emulsions with different affinity for aggregates, cationic and anionic. Asphalt emulsions are used in a wide variety of applications. Chipseal involves spraying the road surface with asphalt emulsion followed by a layer of crushed rock, gravel or crushed slag. Slurry seal involves the creation of a mixture of asphalt emulsion and fine crushed aggregate that is spread on the surface of a road. Cold-mixed asphalt can also be made from asphalt emulsion to create pavements similar to hot-mixed asphalt, several inches in depth, and asphalt emulsions are also blended into recycled hot-mix asphalt to create low-cost pavements.

Main article: Synthetic crude oil See also: Petroleum production in Canada

Synthetic crude oil, also known as syncrude, is the output from a bitumen upgrader facility used in connection with oil sand production in Canada. Bituminous sands are mined using enormous (100 ton capacity) power shovels and loaded into even larger (400 ton capacity) dump trucks for movement to an upgrading facility. The process used to extract the bitumen from the sand is a hot water process originally developed by Dr. Karl Clark of the University of Alberta during the 1920s. After extraction from the sand, the bitumen is fed into a bitumen upgrader which converts it into a light crude oil equivalent. This synthetic substance is fluid enough to be transferred through conventional oil pipelines and can be fed into conventional oil refineries without any further treatment. By 2015 Canadian bitumen upgraders were producing over 1 million barrels (160×10^3 m3) per day of synthetic crude oil, of which 75% was exported to oil refineries in the United States.[76]

In Alberta, five bitumen upgraders produce synthetic crude oil and a variety of other products: The Suncor Energy upgrader near Fort McMurray, Alberta produces synthetic crude oil plus diesel fuel; the Syncrude Canada, Canadian Natural Resources, and Nexen upgraders near Fort McMurray produce synthetic crude oil; and the Shell Scotford Upgrader near Edmonton produces synthetic crude oil plus an intermediate feedstock for the nearby Shell Oil Refinery.[77] A sixth upgrader, under construction in 2015 near Redwater, Alberta, will upgrade half of its crude bitumen directly to diesel fuel, with the remainder of the output being sold as feedstock to nearby oil refineries and petrochemical plants.[78]

See also: Western Canadian Select

Canadian bitumen does not differ substantially from oils such as Venezuelan extra-heavy and Mexican heavy oil in chemical composition, and the real difficulty is moving the extremely viscous bitumen through oil pipelines to the refinery. Many modern oil refineries are extremely sophisticated and can process non-upgraded bitumen directly into products such as gasoline, diesel fuel, and refined asphalt without any preprocessing. This is particularly common in areas such as the US Gulf coast, where refineries were designed to process Venezuelan and Mexican oil, and in areas such as the US Midwest where refineries were rebuilt to process heavy oil as domestic light oil production declined. Given the choice, such heavy oil refineries usually prefer to buy bitumen rather than synthetic oil because the cost is lower, and in some cases because they prefer to produce more diesel fuel and less gasoline.[77] By 2015 Canadian production and exports of non-upgraded bitumen exceeded that of synthetic crude oil at over 1.3 million barrels (210×10^3 m3) per day, of which about 65% was exported to the United States.[76]

Because of the difficulty of moving crude bitumen through pipelines, non-upgraded bitumen is usually diluted with natural-gas condensate in a form called dilbit or with synthetic crude oil, called synbit. However, to meet international competition, much non-upgraded bitumen is now sold as a blend of multiple grades of bitumen, conventional crude oil, synthetic crude oil, and condensate in a standardized benchmark product such as Western Canadian Select. This sour, heavy crude oil blend is designed to have uniform refining characteristics to compete with internationally marketed heavy oils such as Mexican Mayan or Arabian Dubai Crude.[77]

Asphalt was used starting in the 1960s as an hydrophobic matrix aiming to encapsulate radioactive waste such as medium-activity salts (mainly soluble sodium nitrate and sodium sulfate) produced by the reprocessing of spent nuclear fuels or radioactive sludges from sedimentation ponds.[79][80] Bituminised radioactive waste containing highly radiotoxic alpha-emitting transuranic elements from nuclear reprocessing plants have been produced at industrial scale in France, Belgium and Japan, but this type of waste conditioning has been abandoned because operational safety issues (risks of fire, as occurred in a bituminisation plant at Tokai Works in Japan)[81][82] and long-term stability problems related to their geological disposal in deep rock formations. One of the main problem is the swelling of asphalt exposed to radiation and to water. Asphalt swelling is first induced by radiation because of the presence of hydrogen gas bubbles generated by alpha and gamma radiolysis.[83][84] A second mechanism is the matrix swelling when the encapsulated hygroscopic salts exposed to water or moisture start to rehydrate and to dissolve. The high concentration of salt in the pore solution inside the bituminised matrix is then responsible for osmotic effects inside the bituminised matrix. The water moves in the direction of the concentrated salts, the asphalt acting as a semi-permeable membrane. This also causes the matrix to swell. The swelling pressure due to osmotic effect under constant volume can be as high as 200 bar. If not properly managed, this high pressure can cause fractures in the near field of a disposal gallery of bituminised medium-level waste. When the bituminised matrix has been altered by swelling, encapsulated radionuclides are easily leached by the contact of ground water and released in the geosphere. The high ionic strength of the concentrated saline solution also favours the migration of radionuclides in clay host rocks. The presence of chemically reactive nitrate can also affect the redox conditions prevailing in the host rock by establishing oxidizing conditions, preventing the reduction of redox-sensitive radionuclides. Under their higher valences, radionuclides of elements such as selenium, technetium, uranium, neptunium and plutonium have a higher solubility and are also often present in water as non-retarded anions. This makes the disposal of medium-level bituminised waste very challenging.

Different type of asphalt have been used: blown bitumen (partly oxidized with air oxygen at high temperature after distillation, and harder) and direct distillation bitumen (softer). Blown bitumens like Mexphalte, with a high content of saturated hydrocarbons, are more easily biodegraded by microorganisms than direct distillation bitumen, with a low content of saturated hydrocarbons and a high content of aromatic hydrocarbons.[85]

Concrete encapsulation of radwaste is presently considered a safer alternative by the nuclear industry and the waste management organisations.

Roofing shingles account for most of the remaining asphalt consumption. Other uses include cattle sprays, fence-post treatments, and waterproofing for fabrics. Asphalt is used to make Japan black, a lacquer known especially for its use on iron and steel, and it is also used in paint and marker inks by some exterior paint supply companies to increase the weather resistance and permanence of the paint or ink, and to make the color darker.[86] Asphalt is also used to seal some alkaline batteries during the manufacturing process.

Typical asphalt plant for making asphalt

About 40,000,000 tons were produced in 1984.[needs update] It is obtained as the "heavy" (i.e., difficult to distill) fraction. Material with a boiling point greater than around 500 °C is considered asphalt. Vacuum distillation separates it from the other components in crude oil (such as naphtha, gasoline and diesel). The resulting material is typically further treated to extract small but valuable amounts of lubricants and to adjust the properties of the material to suit applications. In a de-asphalting unit, the crude asphalt is treated with either propane or butane in a supercritical phase to extract the lighter molecules, which are then separated. Further processing is possible by "blowing" the product: namely reacting it with oxygen. This step makes the product harder and more viscous.[5]

Asphalt is typically stored and transported at temperatures around 150 °C (302 °F). Sometimes diesel oil or kerosene are mixed in before shipping to retain liquidity; upon delivery, these lighter materials are separated out of the mixture. This mixture is often called "bitumen feedstock", or BFS. Some dump trucks route the hot engine exhaust through pipes in the dump body to keep the material warm. The backs of tippers carrying asphalt, as well as some handling equipment, are also commonly sprayed with a releasing agent before filling to aid release. Diesel oil is no longer used as a release agent due to environmental concerns.

Main article: Oil sands

Naturally occurring crude bitumen impregnated in sedimentary rock is the prime feed stock for petroleum production from "oil sands", currently under development in Alberta, Canada. Canada has most of the world's supply of natural bitumen, covering 140,000 square kilometres[14] (an area larger than England), giving it the second-largest proven oil reserves in the world. The Athabasca oil sands are the largest bitumen deposit in Canada and the only one accessible to surface mining, although recent technological breakthroughs have resulted in deeper deposits becoming producible by in situ methods. Because of oil price increases after 2003, producing bitumen became highly profitable, but as a result of the decline after 2014 it became uneconomic to build new plants again. By 2014, Canadian crude bitumen production averaged about 2.3 million barrels (370,000 m3) per day and was projected to rise to 4.4 million barrels (700,000 m3) per day by 2020.[15] The total amount of crude bitumen in Alberta that could be extracted is estimated to be about 310 billion barrels (50×10^9 m3),[8] which at a rate of 4,400,000 barrels per day (700,000 m3/d) would last about 200 years.

Main articles: Peak oil, Global warming, and Bioasphalt

Although uncompetitive economically, asphalt can be made from nonpetroleum-based renewable resources such as sugar, molasses and rice, corn and potato starches. Asphalt can also be made from waste material by fractional distillation of used motor oil, which is sometimes otherwise disposed of by burning or dumping into landfills. Use of motor oil may cause premature cracking in colder climates, resulting in roads that need to be repaved more frequently.[87]

Nonpetroleum-based asphalt binders can be made light-colored. Lighter-colored roads absorb less heat from solar radiation, reducing their contribution to the urban heat island effect.[88] Parking lots that use asphalt alternatives are called green parking lots.

Selenizza is a naturally occurring solid hydrocarbon bitumen found in native deposits in Selenice, in Albania, the only European asphalt mine still in use. The bitumen is found in the form of veins, filling cracks in a more or less horizontal direction. The bitumen content varies from 83% to 92% (soluble in carbon disulphide), with a penetration value near to zero and a softening point (ring and ball) around 120 °C. The insoluble matter, consisting mainly of silica ore, ranges from 8% to 17%.

Albanian bitumen extraction has a long history and was practiced in an organized way by the Romans. After centuries of silence, the first mentions of Albanian bitumen appeared only in 1868, when the Frenchman Coquand published the first geological description of the deposits of Albanian bitumen. In 1875, the exploitation rights were granted to the Ottoman government and in 1912, they were transferred to the Italian company Simsa. Since 1945, the mine was exploited by the Albanian government and from 2001 to date, the management passed to a French company, which organized the mining process for the manufacture of the natural bitumen on an industrial scale.[89]

Today the mine is predominantly exploited in an open pit quarry but several of the many underground mines (deep and extending over several km) still remain viable. Selenizza is produced primarily in granular form, after melting the bitumen pieces selected in the mine.

Selenizza[90] is mainly used as an additive in the road construction sector. It is mixed with traditional asphalt to improve both the viscoelastic properties and the resistance to ageing. It may be blended with the hot asphalt in tanks, but its granular form allows it to be fed in the mixer or in the recycling ring of normal asphalt plants. Other typical applications include the production of mastic asphalts for sidewalks, bridges, car-parks and urban roads as well as drilling fluid additives for the oil and gas industry. Selenizza is available in powder or in granular material of various particle sizes and is packaged in sacks or in thermal fusible polyethylene bags.

A life-cycle assessment study of the natural selenizza compared with petroleum asphalt has shown that the environmental impact of the selenizza is about half the impact of the road asphalt produced in oil refineries in terms of carbon dioxide emission.[91]

People can be exposed to asphalt in the workplace by breathing in fumes or skin absorption. The National Institute for Occupational Safety and Health (NIOSH) has set a recommended exposure limit of 5 mg/m3 over a 15-minute period.[92]

Asphalt is basically an inert material that must be heated or diluted to a point where it becomes workable for the production of materials for paving, roofing, and other applications. In examining the potential health hazards associated with asphalt, the International Agency for Research on Cancer (IARC) determined that it is the application parameters, predominantly temperature, that affect occupational exposure and the potential bioavailable carcinogenic hazard/risk of the asphalt emissions.[93] In particular, temperatures greater than 199 °C (390 °F), were shown to produce a greater exposure risk than when asphalt was heated to lower temperatures, such as those typically used in asphalt pavement mix production and placement.[94] IARC has classified asphalt as a Class 2B possible carcinogen.

An asphalt mixing plant for hot aggregate
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  38. ^ Salmon, William (1685), Polygraphice; Or, The Arts of Drawing, Engraving, Etching, Limning, Painting, Washing, Varnishing, Gilding, Colouring, Dying, Beautifying and Perfuming (5th ed.), London: R. Jones, pp. 76–77, retrieved 18 August 2010  Text at Internet Archive
  39. ^ "Specification of the Patent granted to Richard Tappin Claridge, of the County of Middlesex, for a Mastic Cement, or Composition applicable to Paving and Road making, covering Buildings and various purposes". Journal of the Franklin Institute of the State of Pennsylvania and Mechanics' Register. Vol. 22. London: Pergamon Press. July 1838. pp. 414–418. Retrieved 18 November 2009. 
  40. ^ "Comments on asphalt patents of R.T. Claridge, Esq". Notes and Queries: A medium of intercommunication for Literary Men, General Readers, etc. Ninth series. Volume XII, July–December, 1903 (9th S. XII, 4 July 1903). London: John C. Francis. 20 January 1904. pp. 18–19.  Writer is replying to note or query from previous publication, cited as 9th S. xi. 30
  41. ^ "Obituary of Frederick Walter Simms". Monthly Notices of the Royal Astronomical Society. London: Strangeways & Walden. XXVI: 120–121. November 1865 – June 1866. Retrieved 12 November 2009. 
  42. ^ Broome, D.C. (1963). "The development of the modern asphalt road". The Surveyor and municipal and county engineer. London. 122 (3278 & 3279): 1437–1440 & 1472–1475Snippet view: Simms & Claridge p.1439 
  43. ^ Phipson, Dr T. Lamb (1902). Confessions of a Violinist: Realities and Romance. London: Chatto & Windus. p. 11. Retrieved 26 November 2009.  Full text at Internet Archive (archive.org)
  44. ^ "Claridge's UK Patents in 1837 & 1838". The London Gazette. 25 February 1851. p. 489. 
  45. ^ a b Hobhouse, Hermione (General Editor) (1994). "British History Online". 'Northern Millwall: Tooke Town', Survey of London: volumes 43 and 44: Poplar, Blackwall and Isle of Dogs. pp. 423–433 (see text at refs 169 & 170). Retrieved 8 November 2009. 
  46. ^ "Claridge's Scottish and Irish Patents in 1838". The Mechanic's magazine, museum, register, journal and gazette. 29. London: W.A. Robertson. 7 April – 29 September 1838. pp. vii, viii, 64, 128. 
  47. ^ a b "Joint Stock Companies (description of asphalte use by Claridge's company)". The Civil Engineer and Architects Journal. Vol. 1. London. October 1837 – December 1838. p. 199. Retrieved 16 November 2009.  Full text at Internet Archive (archive.org). Alternative viewing at: https://books.google.com/books?id=sQ5AAAAAYAAJ&pg
  48. ^ Miles, Lewis (2000), pp.10.06.1–2
  49. ^ a b Comments on asphalt patents of R.T. Claridge, Esq (1904), p.18
  50. ^ a b Miles, Lewis (2000), p.10.06.2
  51. ^ "1838 bitumen UK uses by Robinson's and Claridge's companies, & the Bastenne company". The Mechanic's magazine, museum, register, journal and gazette. 29. London: W.A. Robertson. 22 September 1838. p. 448. 
  52. ^ Gerhard, W.M. Paul (1908). Modern Baths and Bath Houses (1st ed.). New York: John Wiley and Sons.  (Enter "asphalt" into the search field for list of pages discussing the subject)
  53. ^ "Claridge's Patent Asphalte Co. ventures into tarred slag macadam", Concrete and Constructional Engineering, London, IX (1): 760, January 1914, retrieved 15 June 2010 
  54. ^ "Registration of Clarmac Roads", The Law Reports: Chancery Division, Vol. 1: 544–547, 1921, retrieved 17 June 2010 
  55. ^ "Clarmac and Clarphalte", The Building News and Engineering Journal, Vol. 109: July to December 1915 (No. 3157): 2–4 (n13–15 in electronic page field), 7 July 1915, retrieved 18 June 2010 
  56. ^ Roads laid with Clarmac The Building News and Engineering Journal, 1915 109 (3157), p.3 (n14 in electronic field).
  57. ^ a b Clarmac financial difficults due to WW1 Debentures deposited The Law Reports: Chancery Division, (1921) Vol. 1 p.545. Retrieved 17 June 2010.
  58. ^ "Notice of the Winding up of Clarmac Roads", The London Gazette (29340): 10568, 26 October 1915, retrieved 15 June 2010 
  59. ^ a b Claridge's Patent Asphalte Co. compulsorily wound up Funds invested in new company The Law Times Reports (1921) Vol.125, p.256. Retrieved 15 June 2010.
  60. ^ "Claridge's Patent Asphalte Co. winds up 10 November 1917". The London Gazette. 16 November 1917. p. 11863. 
  61. ^ Hobhouse, Hermione (General Editor) (1994). "British History Online". 'Cubitt Town: Riverside area: from Newcastle Drawdock to Cubitt Town Pier', Survey of London: volumes 43 and 44: Poplar, Blackwall and Isle of Dogs. pp. 528–532 (see text at refs 507 & 510). Retrieved 8 November 2009. 
  62. ^ Stockton, Nick (23 June 2017). "Plastic Water Bottles Might Have Poisoned Ancient Californians". Wired. Retrieved 26 June 2017. 
  63. ^ McNichol, Dan (2005). Paving the Way: Asphalt in America. Lanham, MD: National Asphalt Pavement Association. ISBN 0-914313-04-5. Archived from the original on 2006-08-29. 
  64. ^ David O. Whitten, "A Century of Parquet Pavements: Wood as a Paving Material In The United States And Abroad, 1840-1940." Essays in Economic and Business History 15 (1997): 209-26.
  65. ^ Arthur Maier Schlesinger, The Rise of the City: 1878-1898 (1933) p 88-93.
  66. ^ John D. Fairfield, "Rapid Transit: Automobility and Settlement in Urban America" Reviews in American History 23#1 (1995), pp. 80-85 online.
  67. ^ "Robert C. Fitzsimmons (1881–1971)". Canadian Petroleum Hall of Fame. 2010. Retrieved 2016-01-20. 
  68. ^ "Bitumount". Government of Alberta. 2016. Retrieved 2016-01-20. 
  69. ^ Niépce Museum history pages. Retrieved 27 October 2012. Archived 3 August 2007 at the Wayback Machine.
  70. ^ The First Photograph (Harry Ransom Center, University of Texas at Austin). Retrieved 27 October 2012.
  71. ^ Spiegelman, Willard (2009-08-21). "Revolutionary Romanticism: 'The Raft of the Medusa' brought energy to French art". The Wall Street Journal. New York City. Retrieved 2016-01-27. 
  72. ^ The Asphalt Paving Industry: A Global Perspective, 2nd Edition (PDF). Lanham, Maryland, and Brussels: National Asphalt Pavement Association and European Asphalt Pavement Association. February 2011. ISBN 0-914313-06-1. Retrieved 27 September 2012. 
  73. ^ "How Should We Express RAP and RAS Contents?". Asphalt Technology E-News. 26 (2). 2014. Archived from the original on 9 June 2015. Retrieved 2015-08-13. 
  74. ^ "Highway Statistics Series: Public Road Length Miles by Type of Surface and Ownership". Federal Highway Administration. 2013-10-01. Retrieved 2015-08-13. 
  75. ^ "Asphalt Pavement Recycling". Annual Asphalt Pavement Industry Survey on Recycled Materials and Warm-Mix Asphalt Usage: 2009–2013. National Asphalt Pavement Association. Retrieved 13 August 2015. 
  76. ^ a b "Crude Oil and Petroleum Products". National Energy Board of Canada. Retrieved January 21, 2016. 
  77. ^ a b c "2015 CAPP Crude Oil Forecast, Markets & Transportation". Canadian Association of Petroleum Producers. Archived from the original on 20 January 2016. Retrieved January 21, 2016. 
  78. ^ "The Project". North West Redwater Partnership. Retrieved January 21, 2016. 
  79. ^ Rodier, J., Scheidhauer, J., & Malabre, M. (1961). The conditioning of radioactive waste by bitumen (No. CEA-R—1992). CEA Marcoule.
  80. ^ Lefillatre, G., Rodier, J., Hullo, R., Cudel, Y., & Rodi, L. (1969). Use of a thin-film evaporator for bitumen coating of radioactive concentrates (No. CEA-R—3742). CEA Marcoule.
  81. ^ Sato, Y., Miura, A., Kato, Y., Suzuki, H., Shigetome, Y., Koyama, T., ... & Yamanouchi, T. (2000). Study on the cause of the fire and explosion incident at Bituminization Demonstration Facility of PNC Tokai Works. In Nuclear waste: from research to industrial maturity. International conference (pp. 179–190).
  82. ^ Okada, K., Nur, R. M., & Fujii, Y. (1999). The formation of explosive compounds in bitumen/nitrate mixtures. Journal of hazardous materials, 69(3), 245–256.
  83. ^ Johnson, D.I., Hitchon, J.W., & Phillips, D.C. (1986). Further observations of the swelling of bitumens and simulated bitumen wasteforms during γ-irradiation (No. AERE-R—12292). UKAEA Harwell Lab. Materials Development Division.
  84. ^ Phillips, D. C., Hitchon, J. W., Johnson, D. I., & Matthews, J. R. (1984). The radiation swelling of bitumens and bitumenised wastes. Journal of nuclear materials, 125(2), 202–218.
  85. ^ Ait-Langomazino, N., Sellier, R., Jouquet, G., & Trescinski, M. (1991). Microbial degradation of bitumen. Experientia, 47(6), 533–539.
  86. ^ Mohd, Meraj Jafri; Singh, D. K. (march 2013). "Cashew Nutshell Liquid Resin" (PDF). IJRREST: International Journal of Research Review in Engineering Science and Technology. 2: 60–65.  Check date values in: |date= (help)
  87. ^ Hesp, Simon A.M.; Herbert F. Shurvell (2010). "X-ray fluorescence detection of waste engine oil residue in asphalt and its effect on cracking in service". International Journal of Pavement Engineering. 11 (6): 541–553. doi:10.1080/10298436.2010.488729. ISSN 1029-8436. Retrieved 2014-03-24. 
  88. ^ Heat Island Effect. From the website of the US Environmental Protection Agency.
  89. ^ Giavarini, Carlo (March 2013). Six Thousand Years of Asphalt. SITEB. pp. 71–78. ISBN 978-88-908408-3-8. 
  90. ^ [3], Selenice Bitumi for more information about Selenizza
  91. ^ Giavarini, C.; Pellegrini, A. "Life cycle assessment of Selenice asphalt compared with petroleum bitumen". The 1st Albanian Congress on Roads: 234–237. 
  92. ^ "CDC – NIOSH Pocket Guide to Chemical Hazards – Asphalt fumes". www.cdc.gov. Retrieved 2015-11-27. 
  93. ^ IARC (2013). Bitumens and Bitumen Emissions, and Some N- and S-Heterocyclic Polycyclic Aromatic Hydrocarbons. 103. Lyon, France: International Agency for Research on Cancer. ISBN 978-92-832-1326-0. Retrieved 2015-12-07. 
  94. ^ Cavallari, J. M.; Zwack, L. M.; Lange, C. R.; Herrick, R. F.; Mcclean, M. D. (2012). "Temperature-Dependent Emission Concentrations of Polycyclic Aromatic Hydrocarbons in Paving and Built-Up Roofing Asphalts". Annals of Occupational Hygiene. 56 (2): 148–160. doi:10.1093/annhyg/mer107 . ISSN 0003-4878. 
  95. ^ "Contacto – Eco Roofing". epdmecoroofing.com. 
  96. ^ "Follow the evolution of the road from path to pavement". 


Alley

Paver Repair Cost Estimate   (Redirected from Asphalt pavement) A road being resurfaced

A road surface or pavement is the durable surface material laid down on an area intended to sustain vehicular or foot traffic, such as a road or walkway. In the past, gravel road surfaces, cobblestone and granite setts were extensively used, but these surfaces have mostly been replaced by asphalt or concrete laid on a compacted base course. Road surfaces are frequently marked to guide traffic. Today, permeable paving methods are beginning to be used for low-impact roadways and walkways. Pavements are crucial to countries such as US and Canada, which heavily depend on road transportation. Therefore, research projects such as Long-Term Pavement Performance are launched to optimize the life-cycle of different road surfaces.[1][2]

Red surfacing for the bicycle lane in the Netherlands

Closeup of asphalt on a driveway

Asphalt (specifically, asphalt concrete), sometimes called flexible pavement due to the nature in which it distributes loads, has been widely used since the 1920s. The viscous nature of the bitumen binder allows asphalt concrete to sustain significant plastic deformation, although fatigue from repeated loading over time is the most common failure mechanism. Most asphalt surfaces are laid on a gravel base, which is generally at least as thick as the asphalt layer, although some 'full depth' asphalt surfaces are laid directly on the native subgrade. In areas with very soft or expansive subgrades such as clay or peat, thick gravel bases or stabilization of the subgrade with Portland cement or lime may be required. Polypropylene and polyester geosynthetics have also been used for this purpose[3] and in some northern countries, a layer of polystyrene boards have been used to delay and minimize frost penetration into the subgrade.[4]

Depending on the temperature at which it is applied, asphalt is categorized as hot mix, warm mix, or cold mix. Hot mix asphalt is applied at temperatures over 300 °F (150 °C) with a free floating screed. Warm mix asphalt is applied at temperatures of 200–250 °F (95–120 °C), resulting in reduced energy usage and emissions of volatile organic compounds.[5] Cold mix asphalt is often used on lower-volume rural roads, where hot mix asphalt would cool too much on the long trip from the asphalt plant to the construction site.[6]

An asphalt concrete surface will generally be constructed for high-volume primary highways having an average annual daily traffic load greater than 1200 vehicles per day.[7] Advantages of asphalt roadways include relatively low noise, relatively low cost compared with other paving methods, and perceived ease of repair. Disadvantages include less durability than other paving methods, less tensile strength than concrete, the tendency to become slick and soft in hot weather and a certain amount of hydrocarbon pollution to soil and groundwater or waterways.

In the mid-1960s, rubberized asphalt was used for the first time, mixing crumb rubber from used tires with asphalt.[8] While a potential use for tires that would otherwise fill landfills and present a fire hazard, rubberized asphalt has shown greater incidence of wear in freeze-thaw cycles in temperate zones due to non-homogeneous expansion and contraction with non-rubber components. The application of rubberized asphalt is more temperature-sensitive, and in many locations can only be applied at certain times of the year.[citation needed]

Study results of the long-term acoustic benefits of rubberized asphalt are inconclusive. Initial application of rubberized asphalt may provide 3–5 decibels (dB) reduction in tire-pavement source noise emissions; however, this translates to only 1–3 decibels (dB) in total traffic noise level reduction (due to the other components of traffic noise). Compared to traditional passive attenuating measures (e.g., noise walls and earth berms), rubberized asphalt provides shorter-lasting and lesser acoustic benefits at typically much greater expense.[citation needed]

Concrete roadway in San Jose, California Further information: Concrete

Concrete surfaces (specifically, Portland cement concrete) are created using a concrete mix of Portland cement, coarse aggregate, sand and water. In virtually all modern mixes there will also be various admixtures added to increase workability, reduce the required amount of water, mitigate harmful chemical reactions and for other beneficial purposes. In many cases there will also be Portland cement substitutes added, such as fly ash. This can reduce the cost of the concrete and improve its physical properties. The material is applied in a freshly mixed slurry, and worked mechanically to compact the interior and force some of the cement slurry to the surface to produce a smoother, denser surface free from honeycombing. The water allows the mix to combine molecularly in a chemical reaction called hydration.

A concrete road in Ewing, New Jersey. The original pavement was laid in the 1950s and has not been significantly altered since.

Concrete surfaces have been refined into three common types: jointed plain (JPCP), jointed reinforced (JRCP) and continuously reinforced (CRCP). The one item that distinguishes each type is the jointing system used to control crack development.

One of the major advantages of concrete pavements is they are typically stronger and more durable than asphalt roadways. They also can be grooved to provide a durable skid-resistant surface. A notable disadvantage is that they typically can have a higher initial cost, and can be more time-consuming to construct. This cost can typically be offset through the long life cycle of the pavement. Concrete pavement can be maintained over time utilizing a series of methods known as concrete pavement restoration which include diamond grinding, dowel bar retrofits, joint and crack sealing, cross-stitching, etc. Diamond grinding is also useful in reducing noise and restoring skid resistance in older concrete pavement.[9][10]

The first street in the United States to be paved with concrete was Court Avenue in Bellefontaine, Ohio in 1893.[11][12] The first mile of concrete pavement in the United States was on Woodward Avenue in Detroit, Michigan in 1909.[13] Following these pioneering uses, the Lincoln Highway Association, established in October 1913 to oversee the creation of one of the United States' earliest east-west transcontinental highways for the then-new automobile, began to establish "seedling miles" of specifically concrete-paved roadbed in various places in the American Midwest, starting in 1914 west of Malta, Illinois, while using concrete with the specified concrete "ideal section" for the Lincoln Highway in Lake County, Indiana during 1922 and 1923.[14]

An example of composite pavement: hot-mix asphalt overlaid onto Portland cement concrete pavement

Composite pavements combine a Portland cement concrete sublayer with an asphalt. They are usually used to rehabilitate existing roadways rather than in new construction.

Asphalt overlays are sometimes laid over distressed concrete to restore a smooth wearing surface.[15] A disadvantage of this method is that movement in the joints between the underlying concrete slabs, whether from thermal expansion and contraction, or from deflection of the concrete slabs from truck axle loads, usually causes reflective cracks in the asphalt. To decrease reflective cracking, concrete pavement is broken apart through a break and seat, crack and seat, or rubblization process. Geosynthetics can be used for reflective crack control.[16] With break and seat and crack and seat processes, a heavy weight is dropped on the concrete to induce cracking, then a heavy roller is used to seat the resultant pieces into the subbase. The main difference between the two processes is the equipment used to break the concrete pavement and the size of the resulting pieces. The theory is frequent small cracks will spread thermal stress over a wider area than infrequent large joints, reducing the stress on the overlying asphalt pavement. Rubblization is a more complete fracturing of the old, worn-out concrete, effectively converting the old pavement into an aggregate base for a new asphalt road.[17]

Whitetopping uses Portland cement concrete to resurface a distressed asphalt road.

An asphalt milling machine in Boise, Idaho.

Distressed road materials can be reused when rehabilitating a roadway. The existing pavement is ground or broken up into small pieces, through a process called milling. It can then be transported to an asphalt or concrete plant and incorporated into new pavement, or recycled in place to form the base or subbase for new pavement. Some methods used include:

Main article: Chipseal

Bituminous surface treatment (BST) or chipseal is used mainly on low-traffic roads, but also as a sealing coat to rejuvenate an asphalt concrete pavement. It generally consists of aggregate spread over a sprayed-on asphalt emulsion or cut-back asphalt cement. The aggregate is then embedded into the asphalt by rolling it, typically with a rubber-tired roller. This type of surface is described by a wide variety of regional terms including "chip seal", "tar and chip", "oil and stone", "seal coat", "sprayed seal"[21] or "surface dressing"[22] or as simply "bitumen."

BST is used on hundreds of miles of the Alaska Highway and other similar roadways in Alaska, the Yukon Territory, and northern British Columbia. The ease of application of BST is one reason for its popularity, but another is its flexibility, which is important when roadways are laid down over unstable terrain that thaws and softens in the spring.

Other types of BSTs include micropaving, slurry seals and Novachip. These are laid down using specialized and proprietary equipment. They are most often used in urban areas where the roughness and loose stone associated with chip seals is considered undesirable.

A thin membrane surface (TMS) is an oil-treated aggregate which is laid down upon a gravel road bed, producing a dust-free road.[23] A TMS road reduces mud problems and provides stone-free roads for local residents where loaded truck traffic is negligible. The TMS layer adds no significant structural strength, and so is used on secondary highways with low traffic volume and minimal weight loading. Construction involves minimal subgrade preparation, following by covering with a 50-to-100-millimetre (2.0–3.9 in) cold mix asphalt aggregate.[7] The Operation Division of the Ministry of Highways and Infrastructure in Saskatchewan has the responsibility of maintaining 6,102 kilometres (3,792 mi) of thin membrane surface (TMS) highways.[24]

Otta seal is a low-cost road surface using a 16–30-millimetre (0.63–1.18 in) thick mixture of bitumen and crushed rock.[25]

Main article: Gravel road

Gravel is known to have been used extensively in the construction of roads by soldiers of the Roman Empire (see Roman road) but in 1998 a limestone-surfaced road, thought to date back to the Bronze Age, was found at Yarnton in Oxfordshire, Britain.[26] Applying gravel, or "metalling," has had two distinct usages in road surfacing. The term road metal refers to the broken stone or cinders used in the construction or repair of roads or railways,[27] and is derived from the Latin metallum, which means both "mine" and "quarry".[28] The term originally referred to the process of creating a gravel roadway. The route of the roadway would first be dug down several feet and, depending on local conditions, French drains may or may not have been added. Next, large stones were placed and compacted, followed by successive layers of smaller stones, until the road surface was composed of small stones compacted into a hard, durable surface. "Road metal" later became the name of stone chippings mixed with tar to form the road surfacing material tarmac. A road of such material is called a "metalled road" in Britain, a "paved road" in Canada and the US, or a "sealed road" in parts of Canada, Australia and New Zealand.[29]

A granular surface can be used with a traffic volume where the annual average daily traffic is 1,200 vehicles per day or less.[citation needed] There is some structural strength if the road surface combines a sub base and base and is topped with a double graded seal aggregate with emulsion.[7][30] Besides the 4,929 kilometres (3,063 mi) of granular pavements maintained in Saskatchewan, around 40% of New Zealand roads are unbound granular pavement structures.[24][31]

The decision whether to pave a gravel road or not often hinges on traffic volume. It has been found that maintenance costs for gravel roads often exceed the maintenance costs for paved or surface-treated roads when traffic volumes exceed 200 vehicles per day.[32]

Some communities are finding it makes sense to convert their low-volume paved roads to aggregate surfaces.[33]

Pavers (or paviours), generally in the form of pre-cast concrete blocks, are often used for aesthetic purposes, or sometimes at port facilities that see long-duration pavement loading. Pavers are rarely used in areas that see high-speed vehicle traffic.

Brick, cobblestone, sett, wood plank, and wood block pavements such as Nicolson pavement, were once common in urban areas throughout the world, but fell out of fashion in most countries, due to the high cost of labor required to lay and maintain them, and are typically only kept for historical or aesthetic reasons.[citation needed] In some countries, however, they are still common in local streets. In the Netherlands, brick paving has made something of a comeback since the adoption of a major nationwide traffic safety program in 1997. From 1998 through 2007, more than 41,000 km of city streets were converted to local access roads with a speed limit of 30 km/h, for the purpose of traffic calming.[34] One popular measure is to use brick paving - the noise and vibration slows motorists down. At the same time, it is not uncommon for cycle paths alongside a road to have a smoother surface than the road itself.[35][36]

Likewise, macadam and tarmac pavements can still sometimes[when?] be found buried underneath asphalt concrete or Portland cement concrete pavements, but are rarely[clarification needed] constructed today[when?].

There are also other methods and materials to create pavements that have appearance of brick pavements. The first method to create brick texture is to heat an asphalt pavement and use metal wires to imprint a brick pattern using a compactor to create stamped asphalt. A similar method is to use rubber imprinting tools to press over a thin layer of cement to create decorative concrete. Another method is to use a brick pattern stencil and apply a surfacing material over the stencil. Materials that can be applied to give the color of the brick and skid resistance can be in many forms. An example is to use colored polymer-modified concrete slurry which can be applied by screeding or spraying.[37] Another material is aggregate-reinforced thermoplastic which can be heat applied to the top layer of the brick-pattern surface.[38] Other coating materials over stamped asphalt are paints and two-part epoxy coating.[39]

Roadway surfacing choices are known to affect the intensity and spectrum of sound emanating from the tire/surface interaction.[40] Initial applications of noise studies occurred in the early 1970s. Noise phenomena are highly influenced by vehicle speed.

Roadway surface types contribute differential noise effects of up to 4 dB, with chip seal type and grooved roads being the loudest, and concrete surfaces without spacers being the quietest. Asphaltic surfaces perform intermediately relative to concrete and chip seal. Rubberized asphalt has been shown to give a marginal 3–5 dB reduction in tire-pavement noise emissions, and a marginally discernible 1–3 dB reduction in total road noise emissions when compared to conventional asphalt applications.

See also: Pothole, Crocodile cracking, Rut (roads), and Bleeding (roads) Deteriorating asphalt

As pavement systems primarily fail due to fatigue (in a manner similar to metals), the damage done to pavement increases with the fourth power of the axle load of the vehicles traveling on it. According to the AASHO Road Test, heavily loaded trucks can do more than 10,000 times the damage done by a normal passenger car. Tax rates for trucks are higher than those for cars in most countries for this reason, though they are not levied in proportion to the damage done.[41] Passenger cars are considered to have little practical effect on a pavement's service life, from a materials fatigue perspective.

Other failure modes include aging and surface abrasion. As years go by, the binder in a bituminous wearing course gets stiffer and less flexible. When it gets "old" enough, the surface will start losing aggregates, and macrotexture depth increases dramatically. If no maintenance action is done quickly on the wearing course, potholes will form. The freeze-thaw cycle in cold climates will dramatically accelerate pavement deterioration, once water can penetrate the surface.

If the road is still structurally sound, a bituminous surface treatment, such as a chipseal or surface dressing can prolong the life of the road at low cost. In areas with cold climate, studded tires may be allowed on passenger cars. In Sweden and Finland, studded passenger car tires account for a very large share of pavement rutting.

The physical properties of a stretch of pavement can be tested using a falling weight deflectometer.

Several design methods have been developed to determine the thickness and composition of road surfaces required to carry predicted traffic loads for a given period of time. Pavement design methods are continuously evolving. Among these are the Shell Pavement design method, and the American Association of State Highway and Transportation Officials (AASHTO) 1993 "Guide for Design of Pavement Structures". A new mechanistic-empirical design guide has been under development by NCHRP (Called Superpave Technology) since 1998. A new design guide called Mechanistic Empirical Pavement Design Guide (MEPDG) was developed and is about to be adopted by AASHTO.

Further research by University College London into pavements has led to the development of an indoor, 80-sq-metre artificial pavement at a research centre called Pedestrian Accessibility and Movement Environment Laboratory (PAMELA). It is used to simulate everyday scenarios, from different pavement users to varying pavement conditions.[42] There also exists a research facility near Auburn University, the NCAT Pavement Test Track, that is used to test experimental asphalt pavements for durability.

In addition to repair costs, the condition of a road surface has economic effects for road users. Rolling resistance increases on rough pavement, as does wear and tear of vehicle components. It has been estimated that poor road surfaces cost the average US driver $324 per year in vehicle repairs, or a total of $67 billion. Also, it has been estimated that small improvements in road surface conditions can decrease fuel consumption between 1.8 and 4.7%.[43]

Main article: Road surface marking

Road surface markings are used on paved roadways to provide guidance and information to drivers and pedestrians. It can be in the form of mechanical markers such as cat's eyes, botts' dots and rumble strips, or non-mechanical markers such as paints, thermoplastic, plastic and epoxy.

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